SCIENCE CHINA Materials•2026•DOI: 10.1007/s40843-026-4436-0
Microwave-absorbing materials (MAMs) deployed on naval vessels, aerospace vehicles, and critical electronic systems face coupled electromagnetic, marine salt-spray corrosion, and extreme-temperature loads that legacy single-function absorbers cannot withstand. This review consolidates progress on three environmentally adaptive MAM classes: corrosion-protective, anti-icing, and thermal-management absorbers. The electromagnetic loss and impedance-matching fundamentals are first established, then the synergistic mechanisms, design strategies, and characterization protocols for each class are examined against representative material systems and their measured performance. The analysis identifies a shared design logic—multiscale hierarchical architecture, interfacial polarization engineering, and multifunctional phase integration—while distinguishing the divergent protection mechanisms: barrier and passivation effects for corrosion, surface-energy and latent-heat regulation for anti-icing, and phonon–electron transport decoupling for thermal management. Persistent bottlenecks include the trade-off between impedance matching and protective-layer density, the absence of standardized coupled-field test protocols, and the scarcity of long-term salt-spray and thermal-cycling durability data. Future directions are delineated: intelligent self-adaptive absorbers, multiphysics-coupled simulation frameworks, and environmentally benign multifunctional integration. The review provides a theoretical and technical basis for the design, construction, and engineering scale-up of next-generation high-performance absorbers for aerospace, electronic, and marine equipment.
SCIENCE CHINA Materials•2026•DOI: 10.1007/s40843-026-4498-7
Two-dimensional porphyrin-based hypercrosslinked polymers (TPP-HCPs) were synthesized via room-temperature interfacial polymerization using 5,10,15,20-tetraphenylporphyrin and 1,3,5-trioxane. The resulting TPP-HCPs exhibited a BET surface area of 548 m2 g-1 and a CO2 uptake of 7.97 wt% at 1 bar and 298 K. CuO/TPP-HCPs nanospheres were fabricated by thermal conversion of Cu(NO3)2·3H2O in DMF at 135 °C, using TPP-HCPs as dynamic templates. This in-situ strategy generated CuO nanoparticles within the conjugated porous matrix, facilitating electron transfer and enhancing CO2 access to catalytic centers. In CO2 electroreduction, the composite achieved a total gas Faradaic efficiency exceeding 90% at ~500 mA cm-2 (-1.4 V vs. RHE), with 40.9% for C2H4, 8.2% for CH4, 31.9% for CO, and 12.3% for H2. The catalyst maintained stability over 24 h in an H-cell. These results demonstrate that 2D conjugated polymer-templated catalysts can sustain high-rate CO2 conversion to value-added products, offering a viable route for industrial CO2 utilization.
SCIENCE CHINA Materials•2026•DOI: 10.1007/s40843-026-4395-x
Electrocatalysts in lithium–sulfur (Li–S) batteries accelerate sulfur species redox reactions and restrict polysulfide shuttling, yet ideal electrocatalysts with remarkable bidirectional catalytic effects remain scarce. This work utilizes iron (Fe) to trigger bidirectional catalytic effects in a cobalt (Co) electrocatalyst, generating a metal alloy-based heterostructure of Co-Co7Fe3 dispersed homogeneously on carbon sheets (Co-Co7Fe3/CS). Electrochemical tests and in situ X-ray diffraction disclose significantly enhanced bilateral catalytic activity of Co-Co7Fe3 compared to bare Co, confirmed by self-discharge measurements. Post-cycling investigation validates protection of the Li metal anode from sulfur species corrosion. The Co-Co7Fe3/CS-modified coin cells deliver an exceptional rate capability of 603 mAh g–1 at 5.0 C and steady long-life cycling for 500 cycles at 1.0 and 2.0 C. Under high sulfur loadings and lean electrolyte conditions, an impressive areal capacity with stable cycling is realized. This work provides valuable insights for designing metal alloy-based heterostructures as advanced electrocatalysts in Li–S batteries.
SCIENCE CHINA Materials•2026•DOI: 10.1007/s40843-026-4242-1
Infected bone defects remain a formidable clinical challenge due to the coupled pathologies of bacterial infection and impaired osteogenesis. Conventional treatments often fail to address the dynamic microenvironment, leading to persistent infection and inadequate bone repair. Here, we report a microenvironment-adaptive hydrogel incorporating a Ti3C2Tx MXene-based coordination nanoreactor that orchestrates an immune-osteogenic cascade. The nanoreactor, constructed by coordinating Fe3+ ions onto MXene nanosheets, exhibits pH- and reactive oxygen species (ROS)-responsive release of Fe3+ and MXene, enabling sequential antibacterial and pro-osteogenic activities. In vitro studies demonstrated that the hydrogel eradicated Staphylococcus aureus and Escherichia coli (>99.9% killing) within 6 h via synergistic photothermal and chemodynamic effects, while simultaneously scavenging excess ROS to mitigate oxidative stress. Notably, the released Fe3+ ions promoted M2 macrophage polarization, as evidenced by a 2.5-fold increase in CD206 expression, and subsequently enhanced osteogenic differentiation of bone marrow mesenchymal stem cells (BMSCs), with alkaline phosphatase activity elevated by 1.8-fold and alizarin red staining intensity increased by 2.2-fold. In a rat model of infected calvarial defects, the hydrogel significantly accelerated bone regeneration, achieving a bone volume fraction of 78.4% at 8 weeks post-implantation, compared to 35.2% in the untreated control. Micro-CT and histological analyses confirmed robust new bone formation and complete infection clearance. This study presents a paradigm for designing adaptive biomaterials that integrate infection control and bone regeneration, offering a promising strategy for treating infected bone defects.
SCIENCE CHINA Materials•2026•DOI: 10.1007/s40843-025-3629-3
Electrically pumped lasers with reduced physical dimensions are critical for future optical information processing, storage, and photonic integrated circuits. However, electrical injection in perovskite lasers faces challenges including material instability, non-radiative losses, and Joule heating. Here, we demonstrate an ultralow-threshold perovskite microlaser decorated with gold nanoparticles (AuNPs), enabling simultaneous optical pumping and current injection at ambient temperature. The lasing threshold is reduced to 8.6 μJ/cm², approximately 44% lower than that of pristine devices (15.3 μJ/cm²). The AuNPs, with optimized size, enhance both lasing performance and electrical properties, achieving a current injection density of 2.98 kA/cm². AuNPs accelerate hot-carrier cooling, reducing non-radiative recombination and mitigating Joule heating. The threshold decreases progressively with increasing electrical assist fraction. Stability tests confirm excellent resistance to aging and humidity, with stable lasing output under co-excitation in ambient air. This work underscores the feasibility of electrically driven perovskite microlasers, offering a pathway toward electrically pumped microlaser diodes.
SCIENCE CHINA Materials•2026•DOI: 10.1007/s40843-025-3687-6
P2-Na0.67Ni0.33Mn0.67O2 (NNMO) is a promising cathode for sodium-ion batteries (SIBs) due to its high energy density and operating voltage. However, severe P2-O2 phase transition at high cut-off voltage causes large volume variation, structural degradation, and rapid capacity decay. Ion doping has been explored to suppress this transition, but achieving both high capacity and stability remains challenging. Here, we demonstrate that precise composition regulation enables both. The designed P2-Na0.67Ni0.28Mg0.03Fe0.04Mn0.55Ti0.1O2 retains high electrochemical active element content while effectively suppressing phase transition, leading to outstanding structural stability and fast charge transfer kinetics. This cathode delivers a high specific capacity of 143.5 mAh g−1 at 0.1 C and maintains stable cycling over 1000 cycles. Our work provides a new strategy for rationally designing high-capacity, stable cathode materials for SIBs.
SCIENCE CHINA Materials•2026•DOI: 10.1007/s40843-025-3746-x
The polyanionic compound Na3V2(PO4)2O2F (NVPOF) possesses a stable three-dimensional framework, high theoretical specific capacity, and favorable operating voltage, yet its sluggish Na+ diffusion kinetics and low electronic conductivity impede industrial application. This study proposes a dual regulation strategy combining carbon coating and heat treatment temperature to synergistically enhance crystallinity and electrochemical performance. NVPOF@C-400 and NVPOF@C-600 were synthesized via in-situ dopamine hydrochloride coating followed by heat treatment at 400 °C and 600 °C, respectively. Carbon coating at 600 °C significantly improved crystallinity and increased electronic conductivity by three orders of magnitude through the carbon layer's conductive network. The ~4.5 nm carbon layer effectively suppressed abnormal grain growth and secondary crystallization aggregation at high temperatures, maintaining uniform particle size of approximately 0.36 μm, which shortens Na+ diffusion pathways and prevents ion transport obstruction. Consequently, NVPOF@C-600 delivered a high discharge capacity of 102.5 mAh g−1 at 20 C and retained 96.5% capacity after 10,000 cycles. In a full-cell configuration with hard carbon (HC), NVPOF@C-600//HC achieved an impressive 89.3% capacity retention after 9,000 cycles. This work provides critical insights for practical implementation of high-performance NVPOF cathodes in sodium-ion batteries.
SCIENCE CHINA Materials•2026•DOI: 10.1007/s40843-025-3697-8
Multi-site coupling is a promising strategy for developing highly efficient and CO-resistant hydrogen oxidation reaction (HOR) catalysts for proton exchange membrane fuel cells (PEMFCs). However, designing multifunctional synergistic schemes for single-atom sites remains a significant challenge. Herein, we propose a dual-template-confined oxophilic engineering strategy to construct well-dispersed iridium-nickel (IrNi) atomic dimers adjacent to IrNi nanoclusters on porous nitrogen-doped carbon (IrNi Dimer/NC1.8-PNC). The paired IrNi dimer features an asymmetric Ir-N3 configuration coordinated with heteroatomic Ni-N3O via an N-bridge. Remarkably, IrNi Dimer/NC1.8-PNC exhibits a ~23-fold enhancement in mass activity (4.36 A mg−1 Ir at 20 mV) and 5-fold longer stability compared to benchmarking Pt/C toward HOR, while achieving a high rated power density of 1.18 W cm−2 in PEMFC anode applications. Furthermore, IrNi Dimer/NC1.8-PNC demonstrates superior CO tolerance over monometallic Ir and Pt/C in both half-cell and full-cell devices. Combined experimental and density functional theory studies reveal that oxophilic Ni modulates the electronic environment of Ir through alloying and dimer interactions, thereby enhancing HOR activity. Importantly, the asymmetric IrNi dimer enables efficient CO* and OH* co-adsorption while facilitating CO2* desorption, synergistically mitigating CO poisoning and improving atom utilization efficiency. This work provides a design strategy and fundamental insights for multi-site synergistic catalysts in PEMFC anodes.
Chinese Journal of Environmental Engineering•2026•DOI: 10.12030/j.cjee.202507054
In many Chinese wastewater treatment plants (WWTPs), residual chlorine is still manually monitored at low frequencies, leading to imprecise disinfectant dosing. This study systematically compared four machine learning models—backpropagation (BP) neural network, long short-term memory (LSTM) neural network, random forest (RF), and support vector regression (SVR)—for predicting chlorine consumption (i.e., the difference between chlorine dose and residual chlorine) during non-monitoring periods under different residual chlorine monitoring frequencies (every 1, 2, 4, 6, and 8 h). Using data from Plant A (equipped with online residual chlorine monitoring) and Plants B and C (manual monitoring every 6 h and 8 h, respectively), input variables included online water quality indicators (temperature, flow, NH3-N, CODCr, TP, TN) and chlorine dose. Results showed that at 1-h intervals, LSTM achieved the highest prediction accuracy; at 2–4-h intervals, RF performed best; at 6-h or lower frequencies, BP was superior; SVR performed worst across all frequencies. Validation on Plants B and C confirmed BP's optimal performance under low-frequency conditions, and particle swarm optimization (PSO) significantly improved its accuracy. These findings provide a basis for selecting appropriate machine learning models for chlorine consumption prediction under varying monitoring frequencies, particularly low-frequency manual monitoring, thereby supporting precise disinfectant dosing control.
Chinese Journal of Environmental Engineering•2026•DOI: 10.12030/j.cjee.202507021
The accumulation of heavy metals in soil around municipal solid waste landfills poses potential risks to human health. This study selected a municipal solid waste landfill and monitored the concentrations of eight heavy metals (Zn, Pb, Cd, Ni, Hg, Cu, As, Cr) in surrounding soil. The geo-accumulation index method was used for pollution assessment, and a health risk assessment model recommended by the USEPA, combined with Monte Carlo uncertainty analysis, was employed to evaluate the pollution status and health risks to nearby residents. Results showed that among the eight metals, Pb, Ni, and Cd exceeded risk screening values at 4.26%, 6.38%, and 4.26% of sampling points, respectively. Geo-accumulation indices indicated overall clean conditions (mean < 0), but slight pollution by Pb, Zn, Ni, Hg, and Cd at some points. Probabilistic risk assessment based on Monte Carlo simulation revealed that for both adults and children, the cumulative non-carcinogenic risk was negligible, while carcinogenic risk was acceptable. However, there was a very low probability (approximately 0.2%) of non-carcinogenic risk for children, and probabilities of unacceptable carcinogenic risk were 0.64% for adults and 3.21% for children. Nickel was the primary contributor to carcinogenic risk, and children faced higher health risks than adults. These findings provide a reference for pollution prevention and health risk management of soil around municipal solid waste landfills.
Journal of Environmental Engineering Technology•2026•DOI: 10.13205/j.hjgc.202604011
Reverse osmosis (RO) membrane fouling remains a critical bottleneck in reclaimed water production, yet its spatial heterogeneity over extended operation is poorly understood. This study investigated fouling characteristics and microbial community dynamics on RO membranes after 3.5 years of operation in a full-scale microfiltration-reverse osmosis (MF-RO) system treating reclaimed water. Long-term monitoring showed stable effluent quality (turbidity <0.1 NTU, conductivity <400 μS/cm), but RO inlet pressure exhibited seasonal fluctuations of 15%–22% between summer and winter, attributed to water viscosity changes. Membrane autopsies revealed distinct fouling layers at the inlet (RO1) and outlet (RO2) ends. RO1 featured a dense bio-inorganic composite fouling layer with CaSO4 crystals and rod-shaped microbial aggregates (5–10 μm), dominated by Proteobacteria (77.11%), particularly Alphaproteobacteria (71.49%) and Xanthobacteraceae (35.29%), which secreted extracellular polymeric substances (EPS) to form biofilms. In contrast, RO2, exposed to higher salinity, showed reduced microbial abundance (Proteobacteria decreased to 64.79%) and a shift toward halotolerant taxa, including Microbacteriaceae (23.73%) and Actinobacteriota (24.76%), with EPS secretion increased by 42%. Alphaproteobacteria relative abundance dropped by 19.3%, while Gammaproteobacteria rose to 12.54%. These findings elucidate salinity-driven microbial succession and spatial heterogeneity of fouling, providing a basis for targeted antifouling strategies and 'zonal-graded' cleaning protocols in reclaimed water plants.
The Chinese Journal of Process Engineering•2026•DOI: 10.12034/j.issn.1009-606X.225200
Phosphogypsum, a by-product of wet-process phosphoric acid production, poses severe environmental and safety challenges due to its massive annual output and stockpiling. This study addresses the urgent need for resource utilization by employing phosphogypsum as the primary raw material, supplemented with ground granulated blast furnace slag, fly ash, and type II anhydrite. Two foaming agents, sodium bicarbonate (NaHCO3) and aluminum powder, were used to regulate pore structure, and their effects on ceramsite performance were compared. Under identical preparation conditions, aluminum powder yielded higher 7-day cylinder compressive strength than NaHCO3. Optimal formulations achieved a maximum cylinder compressive strength of 6.5 MPa with a bulk density of 1020 kg/m3, meeting lightweight aggregate concrete strength requirements. Aluminum powder produced closed pores, reducing bulk density to as low as 765 kg/m3, while NaHCO3 generated interconnected pores leading to higher water absorption. XRD, SEM, and BET analyses revealed that strength-contributing phases are calcium silicate hydrate and calcium aluminate hydrate; trace heavy metals (Mo, Ti) hinder their formation, causing structural defects. This work demonstrates a green, non-fired route for phosphogypsum valorization, offering environmental and economic benefits and a pathway for large-scale utilization.
Journal of Environmental Engineering Technology•2026•DOI: 10.13205/j.hjgc.202605018
To address the inadequacy of existing temporal emission allocation coefficients for oil storage, transportation, and sales sources in regions with distinct seasonal temperature variations, this study focused on a large oil depot in Northwest China. A method for establishing temperature-dependent hourly allocation coefficients for VOCs emissions was proposed, revealing a positive correlation between ambient temperature and emission coefficients. The coefficient peaked at 0.068 when temperatures exceeded 14 °C and dropped to a minimum of 0.007 below 8.5 °C. Annual VOCs emissions totaled 256.13 t, with summer contributing 108.89 t (42.51% of annual total) and winter only 12.54 t (4.90%), making summer emissions approximately 8.68 times higher than winter. Using CALPUFF dispersion modeling, dynamic source strength scenarios produced a maximum hourly concentration of 2242.7 μg/m³, a 55.12% increase over the constant source strength scenario (1445.8 μg/m³). The area of exceedance increased by 0.03 km², and the atmospheric environmental protection distance extended by 450 m, from 0 m to 450 m. These results demonstrate that conventional constant emission assumptions underestimate peak concentrations and protection distances, posing health risks to nearby residents. The study provides a scientific basis for localized emission regulation and improved environmental protection distance calculations.
Chinese Journal of Environmental Engineering•2026•DOI: 10.12030/j.cjee.202510041
This study presents a full-scale engineering practice of retrofitting an idle upflow anaerobic sludge blanket (UASB) reactor into an aerobic granular sludge (AGS) system for treating low-strength municipal wastewater. The design capacity was 20,000 m3/d (maximum 24,000 m3/d), achieving separate treatment of industrial and domestic wastewater to reduce operational costs. Systematic analysis covered hydraulic capacity enhancement, effluent quality, pollutant removal efficiencies, sludge granulation progress, and operational costs. Results showed rapid start-up: the system reached 75% of design capacity by day 10 and 90% by day 26. During a 4-month operation, average removal efficiencies for COD, NH4+-N, TN, and SS were 83.2%, 97.0%, 75.9%, and 94.4%, respectively, even under low influent BOD5/TN ratios (typically below 4). Granulation progressed quickly: by day 44, average particle size was 2.6 times that of the inoculum and over 4 times that of flocs, with granules (>200 μm) accounting for 17.3%; by day 110, these values increased to 3.2 times and 5 times, with granule proportion reaching 33.4%. Compared to the previous year (June–August), the AGS process reduced electricity consumption, chemical consumption, and sludge production by 77.3%, 25.4%, and 30.4%, respectively, while saving 65.6% of footprint. This ten-thousand-ton case provides a practical basis for AGS technology application in China.
Journal of Environmental Engineering Technology•2026•DOI: 10.13205/j.hjgc.202606008
Resin-enhanced electrosorption for water treatment significantly improves ion adsorption efficiency and selectivity through synergistic effects, making it a research hotspot in the water treatment field. This technology provides an innovative solution to the bottlenecks of kinetic lag and insufficient selectivity by modulating electrode-solution interface behavior in multiple dimensions. Current technological advances include the following: a simple integration method enables desalination efficiency to exceed 92.3%; resin-coated composite electrodes eliminate the co-ion effect and achieve a 42% increase in total salt adsorption capacity; resin-derived porous carbon electrodes with tunable pore structures possess three to five times the adsorption capacity of commercially available activated carbon; and by enhancing solution convection and electrophoretic convection, the resin-filling strategy achieves a high desalination rate of (670 ± 20) mg/(L·h). Studies have demonstrated that different material combinations can achieve targeted optimization of adsorption performance based on specific water quality characteristics. Future research directions may focus on: developing intelligent resin materials with electromagnetic responsiveness; constructing a multi-scale structural design theory for resin-electrode systems; and establishing a cross-scale model integrating electrochemistry, fluid dynamics, and interface science for comprehensive analysis. In particular, in-depth studies are needed on the dynamic behavior of resin-based flow electrodes under electric/magnetic field regulation, as well as the precise construction of catalytic sites on the resin surface. This review aims to promote the widespread application and efficient practice of this technology in water treatment, providing a theoretical foundation and scientific basis for the future development of high-efficiency, selective, and stable electrosorption technologies.
SCIENCE CHINA Materials•2026•DOI: 10.1007/s40843-026-4053-5
The rapid and efficient removal of radioactive iodine species from water is critical for nuclear waste treatment, particularly given the short half-life of 131I (8.02 days). Traditional porous inorganic materials exhibit low uptake capacities (<1 g g−1), while porous frameworks such as MOFs and COFs achieve high capacities (>5 g g−1) but suffer from slow removal kinetics, often requiring hours to capture 80% of iodine. This study introduces nonporous naphthobipyrrole-based organic cages (NBP-Cages) that demonstrate ultrafast iodine removal from water. Among the materials tested, type-II Me-NBP-Cage and Et-NBP-Cage, prepared via reprecipitation, exhibit amorphous morphology with small particle sizes (2–6 μm) and low BET surface areas (33.4 and 2.3 m2 g−1, respectively). Despite their nonporosity, these materials achieve >99% iodine removal within seconds, outperforming previously reported sorbents. The adsorption performance correlates with particle size and morphology: amorphous, small particles with effective surface gaps show superior kinetics. The materials are recyclable; for instance, Et-NBP-Cage can be regenerated by washing with acetonitrile, maintaining removal efficiency over five cycles. This work highlights the potential of nonporous organic cages as high-performance iodine sorbents, addressing the critical need for materials that combine high uptake capacity with rapid removal kinetics.
Chinese Journal of Environmental Engineering•2026•DOI: 10.12030/j.cjee.202511003
Tailings dam leakage can cause secondary sudden water pollution events, imposing severe combined stress of high turbidity and heavy metal contamination on natural water bodies within a short period, threatening aquatic ecological security. Existing studies have systematically revealed the pollution characteristics and biological effects of such events, which are fundamentally distinct from natural high-turbidity water and industrial wastewater leakage. Compared with natural high-turbidity water, tailings leakage inputs finer particles with higher specific surface area, leading to more intense and prolonged turbidity stress. Meanwhile, heavy metals in tailings are more enriched than natural sediments, with higher proportions of active forms and bioavailability, causing significant bioaccumulation and toxic effects, and long-term decline in benthic community species richness. Compared with industrial wastewater leakage, tailings leakage simultaneously releases high concentrations of fine suspended solids and multiple heavy metals, forming a unique 'physical-chemical' combined stress. This synergistic effect amplifies biological toxicity through multiple pathways such as mechanical damage, light limitation, and oxidative stress, resulting in severe and often irreversible ecological damage, such as impaired fish swimming behavior and collapse of benthic community structure. Analyzing the long-term impacts of tailings leakage on aquatic ecosystems from the perspective of combined stress is helpful for providing scientific basis for emergency response and medium-to-long-term ecological risk prevention of related sudden water pollution events.
Chinese Journal of Environmental Engineering•2026•DOI: 10.12030/j.cjee.202511002
To treat large-air-volume, low-concentration volatile organic compounds (VOCs) containing tetrachloroethylene (PCE) generated from rubber-metal bonding, this study systematically investigated the adsorption-desorption behavior and interaction mechanisms of PCE, toluene, and methyl isobutyl ketone (MIBK) on granular activated carbon (GAC). Static adsorption experiments showed that PCE adsorption capacity reached 556.6 mg·g−1, while dynamic multi-component adsorption capacity was 179.6 mg·g−1. Kinetic analysis indicated that PCE adsorption was controlled by both intraparticle diffusion and external surface adsorption, whereas toluene and MIBK were primarily intraparticle diffusion-limited. During high-temperature nitrogen desorption, PCE underwent dechlorination, hydrogenation, and recombination, producing trichloroethylene, 1,2-dichloroethane, 1,2-dichloropropane, and HCl, with HCl accounting for 3.61% of the chlorine molar content in adsorbed PCE. After four adsorption-desorption cycles, the iodine value of GAC dropped below the industry standard of 600 mg·g−1; however, water washing and alkali immersion extended the cycle life to 8 and 9 cycles, respectively. The HCl generation pattern in co-adsorption systems was consistent with single-PCE systems. A regeneration process combining alkali immersion and water washing was proposed and integrated into an engineering strategy. Compared to conventional activated carbon adsorption coupled with RTO incineration, the proposed classification strategy reduced annual costs by 49.5×10⁴ CNY. This work provides a cost-effective and safe solution for Cl-VOCs treatment.
Journal of Fuel Chemistry and Technology•2026•DOI: 10.1016/S1872-5813(26)60659-7
Coal gasification fine slag (CGFS), a solid waste from entrained-flow coal gasification, is characterized by fine particles and high silicon and aluminum content. This study proposes a simple and economical hydrothermal synthesis of ZSM-5 molecular sieve using CGFS as raw material. Impurities were removed by acid washing, followed by alkaline extraction of silicon and aluminum species. The extracted Si-Al precursors were crystallized hydrothermally at 170 °C for 48 h, yielding ZSM-5 with a high specific surface area of 358 m2/g. Adsorption experiments showed that the synthesized ZSM-5 exhibited excellent Pb2+ removal performance: at 25 °C, the removal efficiency for a 50 mg/L Pb2+ solution reached 83.7%, with an adsorption capacity of 104.625 mg/g under optimized conditions. The adsorption process is mainly governed by chemisorption mechanisms, including surface complexation, precipitation, and ion exchange. Thermodynamic analyses indicated that Pb2+ adsorption is spontaneous and endothermic, consistent with multilayer chemisorption. The synthesized ZSM-5 shows promising potential for application in the treatment of lead-containing wastewater, offering a high-value utilization route for coal-based solid waste.
Environmental Chemistry•2026•DOI: 10.7524/j.issn.0254-6108.2025032401
Diazepam (DZP), a benzodiazepine anxiolytic drug, has been a persistent contaminant in fishery water environments. In China, DZP is classified as a veterinary drug that must not be detected in animal-derived foods, yet it is frequently found in aquatic products, posing significant risks to ecological health and food safety. This review systematically summarizes the current pollution status of DZP in fishery water and its adverse effects on aquatic organisms, emphasizing its persistence in both water and aquatic products. The paper comprehensively examines advances in detection techniques, including gas chromatography-mass spectrometry (GC-MS) and liquid chromatography-tandem mass spectrometry (LC-MS/MS), as well as treatment technologies such as adsorption, photolysis, chemical oxidation, and biodegradation. Critical gaps remain in the integration of these technologies for practical remediation. The review underscores the urgent need for enhanced monitoring and risk assessment of DZP contamination, alongside the development of more efficient and scalable treatment methods. By consolidating current knowledge, this work provides technical support for aquatic organism protection and fishery water management, and serves as a reference for future research and technological innovation in this field.
SCIENCE CHINA Materials•2026•DOI: 10.1007/s40843-025-3946-2
High energy-density lithium–sulfur (Li–S) batteries with rapid intermediate conversion and forbidden shuttle effect require superior electrocatalysts with tunable catalytic activity. In this protocol, binary FeNi3 alloy nanoparticles homogeneously embedded within carbon nanosheets (FeNi3/CNS) are synthesized to regulate the conversions of sulfur species. Time of flight-secondary mass ion spectroscopy reveals a significantly improved catalytic effect of binary FeNi3 alloy compared to bare Ni, which is confirmed by a larger Li2S amount generated during in situ X-ray diffraction measurement. Further anode characterization validates efficient shuttling suppression and good lithium metal protection. In Li–S batteries, electrochemical tests demonstrate a remarkable rate capability of 852 mAh g−1 at 3.0 C, and outstanding long-term cycle at 1.0 C (639 mAh g−1 after 500 cycles). Even under a wide operation temperature range (−15–60 °C), Li–S batteries exhibit stable cycling with high specific capacities under high current rates. Moreover, Li–S batteries using FeNi3/CNS attain a maximum areal capacity of 5.60 mAh cm−2 under ~4.0 mg cm−2 sulfur. This study highlights the advantages of adopting binary or multi-component metal alloys as electrocatalysts and points out the research directions to advance Li–S batteries into practical applications.
Chinese Journal of Environmental Engineering•2026•DOI: 10.12030/j.cjee.202511050
Municipal solid waste (MSW) management in Inner Mongolia has long relied on landfilling, facing land scarcity and leachate management challenges. This study addresses the region's dry, cold climate, high proportion of agricultural and livestock waste, fluctuating moisture content, and weak leachate treatment capacity. An engineering optimization was implemented on an 80 t·d−1 vertical rotary gasification-incineration system featuring a dual-combustion-chamber design (primary chamber for medium-temperature pyrolysis-gasification at 550–650 °C and secondary chamber for high-temperature oxidation above 900 °C), coupled with in-situ leachate recirculation. Field measurements showed improved processing capacity and continuous operation stability. Under the project's leachate yield, in-situ recirculation achieved on-site disposal without significant adverse effects on gasification-incineration conditions, providing buffering against moisture fluctuations. During the monitoring period, major gaseous pollutant emissions remained below current national standards. The results provide engineering references for the co-processing and stable operation of small-scale county-level MSW treatment facilities.
SCIENCE CHINA Materials•2026•DOI: 10.1007/s40843-025-3999-x
The integration of photochromism (PhCh) and persistent luminescence (PersL) into a single material remains a formidable challenge due to the complex role of defects in modulating optical properties. Here, we employ structurally simple CsX (X = Cl, Br) nanocrystals (NCs) as a model system to elucidate the relationship between defects and optical behaviors. We demonstrate that CsX NCs accommodate two distinct types of chlorine vacancy defects upon X-ray irradiation: intrinsic vacancies from synthesis and X-ray-induced vacancies. This dual-defect engineering enables reversible blue coloration under X-ray irradiation (20–70 kV), attributed to recoverable chlorine vacancies that are rapidly eliminated by visible light within 30 s. The photochromic behavior exhibits excellent cycling stability with a color difference (ΔRL1) of 56.9% and a recovery rate (ΔRL2) of 98.1%. Furthermore, Br− incorporation deepens the energy level of intrinsic chlorine vacancies from 0.47–0.71 eV to 0.83 eV, resulting in intense persistent luminescence lasting over 30 minutes. These dual-mode PhCh–PersL characteristics position CsX NCs as promising candidates for X-ray colorimetric imaging and dynamic anti-counterfeiting applications. Our findings establish a defect-oriented design principle extendable to other halide systems, advancing the development of multifunctional photonic materials.