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Showing 24 of 1398 peer-reviewed translated articles (Page 33 of 59)

Heat-Shrinkable Thermoplastic Films Enable Universal Conformal Electronics via Semi-Liquid Metal CircuitsGraphical AbstractVerified
SCIENCE CHINA Materials2026

Heat-Shrinkable Thermoplastic Films Enable Universal Conformal Electronics via Semi-Liquid Metal Circuits

Conformal electronics that seamlessly adhere to three-dimensional (3D) surfaces are critical for wearable devices, bio-integrated sensing, and human-machine interfaces. However, existing methods—such as in-situ printing on curved surfaces or planar fabrication followed by lamination—struggle with high costs, complex motion control, or poor adhesion on irregular geometries. Here, we highlight a recent breakthrough by Jiang et al. (Nature Electronics, 2026) that employs heat-shrinkable thermoplastic films to achieve precise conformal mapping of electronic circuits onto arbitrary 3D surfaces. The method involves printing a semi-liquid-metal composite ink—comprising silver-coated copper particles dispersed in eutectic gallium-indium alloy (EGaIn)—onto pre-stretched polyvinyl chloride (PVC) films. Upon heating to approximately 70 °C, the film shrinks, generating compressive strain that drapes the circuit onto the target substrate. The composite ink maintains metal-level conductivity (9.5×10^6 S m^-1) and exhibits roughly doubled viscosity relative to neat EGaIn, preventing fracture and agglomeration during shrinkage. A poly(methyl methacrylate) (PMA) interfacial layer ensures stable adhesion. Finite element simulation enables pre-deformation pattern design, accurately predicting post-shrinkage layouts. The process is rapid (~5 s) and simple, successfully conforming to diverse surfaces including ceramics, metals, fruit peels, polytetrafluoroethylene (PTFE), and wet wood, with minimal resistance change. This strategy departs from reliance on intrinsic material stretchability, offering a cost-effective, universal route for conformal electronics with broad application potential in healthcare, environmental sensing, and intelligent interaction.

Read Full Abstract10.1007/s40843-026-4041-1
Ion Association in Nanoconfinement for Precision SeparationGraphical AbstractVerified
SCIENCE CHINA Materials2026

Ion Association in Nanoconfinement for Precision Separation

Selective ion transport in spatial confinement is central to environmental and energy sustainability, including desalination, energy conversion, and resource recovery. While biomimetic nanochannel membranes often rely on size exclusion or fixed ion-channel interactions, real-world separation systems involve multicomponent ionic mixtures where ion-ion interactions, such as dynamic pairing and competition, play a decisive yet underexplored role. Pan and coworkers address this gap by developing a functionalized membrane enabling dynamic manipulation of ion-ion interactions triggered by external ionic stimuli, achieving precise and reversible control over target ion transport. The membrane is constructed from aligned MXene nanosheets functionalized with γ-PGA through covalent and hydrogen bonding, establishing well-defined spatial confinements and adjacent amino and carboxyl groups that serve as anion-cation binding sites. This design enhances ion-pair formation, yielding ion selectivity and stimulus-responsive performance rivalling biological channels. Notably, when K+ and Mg2+ co-permeate, anions preferentially associate with K+ within the nanochannel, disrupting Mg2+ transport despite Mg2+'s higher affinity for channel walls. The MLM–γ-PGA membrane exhibits uniform channel architecture and remarkable aqueous stability. Ion transport characterization using a U-shaped diffusion cell with chloride salt solutions shows that with 0.2 M MgCl2 feed, Mg2+ permeation rate is 3.16 × 10−3 mol m−2 h−1. Introducing 0.2 M KCl suppresses Mg2+ permeation by two orders of magnitude to 3.2 × 10−5 mol m−2 h−1, with full reversibility over multiple cycles. This work highlights the potential of exploiting ion-ion interactions in nanoconfinement for precision separation.

Read Full Abstract10.1007/s40843-025-3868-y
Three-dimensional microchannel design redefines strain-insensitive multifunctional liquid metal yarnsGraphical AbstractVerified
SCIENCE CHINA Materials2026

Three-dimensional microchannel design redefines strain-insensitive multifunctional liquid metal yarns

The emergence of smart textiles and wearable electronics demands conductive fibers that maintain stable electrical performance under dynamic mechanical deformation. Conventional conductive yarns, based on carbon nanomaterials, metallic coatings, or hybrids, suffer from a trade-off between conductivity and stretchability, often exhibiting resistance fluctuations or failure under strain. Liquid metals (LM) offer high conductivity and intrinsic deformability but suffer from interfacial instability, such as dewetting and leakage, without structural guidance. This work presents a hierarchical design strategy integrating capillary-guided infiltration and interfacial anchoring of LM within yarn microstructures. Electrospun poly(styrene-block-butadiene-block-styrene) (SBS) microfibers onto commercial spandex (PU) yarns create a porous base with three-dimensional microchannels. These channels are functionalized with silver nanoparticles (AgNPs) to enhance wettability and provide reactive sites for alloying with LM. Upon immersion, LM is drawn into the porous network via capillary action, forming stable intermetallic bonds (Ag9In4 and AgIn2) with the AgNP-modified fibers. Encapsulation with a second SBS layer yields the final SBS-LM/Ag-SBS (SLMAS) yarn. The resulting yarns exhibit exceptional electrical conductivity, with resistance as low as 0.082 Ω/cm at an LM loading of 6.88 mg/cm. They demonstrate strain-invariant performance, long-term durability, and functional convergence, supporting Joule heating and electrochromic display within a single fiber. Joule heating tests show a temperature rise from 86.4 to 122.7°C, following Ohm's and Joule's law. Integration of thermochromic microcapsules enables voltage-triggered color change, laying groundwork for electrothermally responsive textiles. Challenges remain in material costs, multi-step fabrication, and durability under environmental stressors. This work establishes a new paradigm for stretchable fiber electronics, reconciling conductivity with extreme mechanical compliance.

Read Full Abstract10.1007/s40843-025-3720-2
Re-entrant Phase Behavior of Organic Semiconductors: A Thermodynamic Framework for Designing Stable Non-Fullerene Organic Solar CellsGraphical AbstractVerified
SCIENCE CHINA Materials2026

Re-entrant Phase Behavior of Organic Semiconductors: A Thermodynamic Framework for Designing Stable Non-Fullerene Organic Solar Cells

The stability of organic solar cells (OSCs) is a critical bottleneck for their commercialization. This study introduces a low-free-energy, two-state (LF-TSB) model to describe the re-entrant phase behavior observed in blends of small molecule acceptors (SMAs) and semiconducting polymers. The model integrates molecular rigidity (glass transition temperature, T_g), side-chain architecture (effective monomeric volume), and molecular symmetry (configurational entropy) to predict phase diagrams. Experimental validation using SMA:polymer blends demonstrates that suppressed driving force for phase separation, achieved by modulating these molecular parameters, leads to superior thermal stability. For instance, blends with reduced molecular rigidity and optimized side-chain volume exhibit stable morphology over extended thermal stress. The model also explains the re-entrant phase transition, where a homogeneous blend becomes unstable at intermediate temperatures but re-stabilizes at higher temperatures, enabling multi-step annealing strategies to trap beneficial morphological states. While the LF-TSB model shows predictive potential, challenges remain in determining new parameters (e.g., effective monomeric volume, flexing energy) a priori for novel systems, and its applicability to other blend types (polymer-polymer, small molecule-small molecule, hydrogels) requires further exploration. This work provides new guidelines for designing stable OSCs by rationally tailoring molecular parameters to achieve desired phase morphology.

Read Full Abstract10.1007/s40843-025-3735-x
Correction to: Gene Silencing-Mediated Immune Checkpoint Blockade for Tumor Therapy Boosted by Dendrimer-Entrapped Gold NanoparticlesGraphical AbstractVerified
SCIENCE CHINA Materials2026

Correction to: Gene Silencing-Mediated Immune Checkpoint Blockade for Tumor Therapy Boosted by Dendrimer-Entrapped Gold Nanoparticles

This correction addresses an inadvertent duplication error in Fig. 4d of the original article published in Sci China Mater 2021, 64(8): 2045–2055. The TUNEL staining image of tumor tissue in the PBS group was mistakenly duplicated with the Vector/siNC group during figure assembly. The corrected Fig. 4 is provided, which includes the timeline for in vivo tumor immunotherapy, relative tumor volume changes (n=6 per group; **p<0.01, ***p<0.001), relative mouse body weight variations, and H&E and TUNEL staining of tumor sections on day 14. The correction does not alter the overall results, interpretation, or conclusions of the study. The original research demonstrated that dendrimer-entrapped gold nanoparticles (Au DENPs) can effectively deliver siRNA for gene silencing, thereby boosting immune checkpoint blockade for tumor therapy. The study highlighted the potential of this nanoplatform for combined gene therapy and immunotherapy in cancer treatment.

Read Full Abstract10.1007/s40843-025-3609-0
Insights from the EU Green Claims Directive and Related Policies for Carbon Dioxide Removal in ChinaGraphical AbstractVerified
Chinese Journal of Environmental Engineering2026

Insights from the EU Green Claims Directive and Related Policies for Carbon Dioxide Removal in China

Amid intensifying global warming, carbon emission reduction and carbon dioxide removal (CDR) have become central to climate governance. In March 2023, the European Commission proposed the Green Claims Directive (GCD) to combat greenwashing and enhance the reliability, comparability, and verifiability of environmental claims. The GCD, together with the Empowering Consumers for the Green Transition Directive, the Carbon Removal Certification Framework, and the European Sustainability Reporting Standards, forms a policy cluster supporting the EU's green transition and CDR deployment. China, as a major greenhouse gas emitter, has made progress in renewable energy and national carbon market construction, yet its total emissions remain high, CDR technologies are nascent, and CCUS deployment is economically oriented, mainly in enhanced oil recovery. This study systematically reviews the legislative background, core objectives, and synergistic logic of the GCD and related policies, focusing on requirements for CDR certification, third-party verification, and carbon credit regulation. It compares Chinese and EU carbon markets in coverage, allowance allocation, and MRV systems. The analysis indicates that EU experience in policy integration, technical standardization, and market maturity can inform China's policy framework, technology pathways, and market efficiency, supporting large-scale CDR and the 'dual carbon' goals.

Read Full Abstract10.12030/j.cjee.202509093
Comparative Optimization and Equipment Development of Enrichment and Concentration Methods for SARS-CoV-2 in Wastewater from Inbound FlightsGraphical AbstractVerified
Chinese Journal of Environmental Engineering2026

Comparative Optimization and Equipment Development of Enrichment and Concentration Methods for SARS-CoV-2 in Wastewater from Inbound Flights

This study systematically compared three virus enrichment and concentration methods—polyethylene glycol (PEG) precipitation, aluminum salt coagulation, and centrifugal ultrafiltration—for detecting SARS-CoV-2 in high-turbidity, high-strength wastewater from inbound flights. The aluminum salt coagulation method exhibited the best overall performance, achieving an average recovery rate of 25.95% for SARS-CoV-2 pseudovirus, significantly higher than PEG precipitation (12.91%) and centrifugal ultrafiltration (0.22%) (P<0.05). Its detection limit reached 10 copies·mL⁻¹, whereas centrifugal ultrafiltration suffered severe membrane fouling, limiting detection to 1,000 copies·mL⁻¹. Considering the high pH buffering of flight wastewater, the aluminum salt method was optimized by adjusting pH to 6.00±0.4, employing rapid magnetic stirring, and reducing mixing time to 1 minute, yielding an average recovery of 27.56% (not significantly different from the original 25.95%, P>0.05). An automated enrichment device was developed based on the optimized method, reducing processing time per sample from 115 min to 60 min while maintaining comparable recovery and improved repeatability. Applied to 1,309 wastewater samples from inbound flights between January 2024 and May 2025, the average detection rate of SARS-CoV-2 was 45.45%, with trends consistent with national COVID-19 epidemiological data. The automated device demonstrates suitability for routine surveillance, providing technical support for port epidemic prevention.

Read Full Abstract10.12030/j.cjee.202509049
A dual enzyme-mimicking COF sonosensitizer potentiates cancer sonodynamic therapy via cascade oxygenation and ROS stormGraphical AbstractVerified
SCIENCE CHINA Materials2026

A dual enzyme-mimicking COF sonosensitizer potentiates cancer sonodynamic therapy via cascade oxygenation and ROS storm

Sonodynamic therapy (SDT) faces critical limitations from inefficient sonosensitizers and the hypoxic tumor microenvironment, which curtail reactive oxygen species (ROS) generation. Here, we report a dual enzyme-mimicking sonosensitizer, termed sonozyme, engineered by integrating platinum nanoparticles (Pt NPs) with a tailored covalent organic framework (Y-COF). The spatially separated donor-acceptor architecture optimizes the band position of Y-COF, conferring intrinsic sonodynamic activity. Pt NPs further enhance ultrasound-triggered ROS generation by promoting exciton separation and transfer. Notably, sonozyme exhibits catalase (CAT) and peroxidase (POD) mimetic activities, converting endogenous H2O2 into O2 and ·OH, thereby alleviating hypoxia and augmenting oxidative stress. In vitro assays demonstrated significantly enhanced ROS production and cancer cell death under ultrasound irradiation. In vivo studies confirmed that sonozyme effectively suppresses tumor progression without observable systemic toxicity. This work presents a paradigm for designing high-performance multifunctional sonosensitizers, offering a promising strategy for cancer therapy.

Read Full Abstract10.1007/s40843-025-3806-0
Ultrathin and flexible electromagnetic interference shielding films by interface-confinement strategyGraphical AbstractVerified
SCIENCE CHINA Materials2026

Ultrathin and flexible electromagnetic interference shielding films by interface-confinement strategy

Electromagnetic interference (EMI) shielding technology is evolving from traditional bulky metal enclosures toward ultrathin, conformable, and flexible films. However, as the thickness of the shielding layer decreases, the electromagnetic wave absorption efficiency significantly deteriorates, leading to a marked decline in overall shielding performance. To overcome this intrinsic 'thickness–performance dilemma', porous structural designs are often employed to enhance multiple internal reflections and absorption. Nevertheless, such strategies typically suffer from uncontrollable thickness, poor spatial uniformity, and low process compatibility. To address these challenges, a joint team from the Gwangju Institute of Science and Technology and Seoul National University proposed an embedded MXene-in-metal (EXIM) shielding strategy. By embedding a non-porous MXene layer within a metallic film, a metal–MXene–metal heterolamellar architecture was constructed. Remarkably, this ultrathin structure achieves an EMI shielding effectiveness of ~70 dB at only ~1 μm thickness (up to 80 dB at 1.9 μm), breaking the conventional trade-off between reduced thickness and performance degradation. The superior performance originates from the conductivity contrast between the metal and MXene layers, which forms electromagnetic confinement wells. The localized electromagnetic waves undergo multiple polarization losses induced by interfacial dipoles, resulting in efficient energy absorption at thin thicknesses. The study further reveals that the EMI shielding performance of EXIM films primarily depends on the number of metal–MXene heterointerfaces rather than the total thickness. Multilayer stacking (e.g., Cu/Ti3C2Tx/Cu) notably enhances absorption efficiency while imparting excellent isotropy and flexibility. Moreover, introducing a Cr–Al dual-metal passivation layer effectively suppresses MXene oxidation, ensuring long-term operational reliability. The EXIM films are compatible with conventional fabrication and packaging techniques, including physical vapor deposition and spray coating, enabling scalable and large-area production. Practical demonstrations in USB 3.0 chips and flexible Schottky diodes confirm their outstanding capability in mitigating Bluetooth interference and blocking electromagnetic noise. This work is pioneering in that it introduces a new shielding mechanism based on conductivity contrast-induced electromagnetic confinement, achieves ultrahigh shielding effectiveness and mechanical flexibility within an ultrathin (<2 μm) structure, and elucidates a dipole-dominated interfacial polarization loss mechanism that provides theoretical insights into the design of 2D-material-based heterostructured shielding systems. Moreover, it opens up a new path for EMI shielding to shift from 'thick structure reflection' to 'heterogeneous interface confined absorption', providing a novel solution for realizing free-form, interference-free intelligent electronic packaging.

Read Full Abstract10.1007/s40843-025-3876-5
Life-Cycle Carbon Footprint Assessment and Emission Reduction Strategy Analysis of Ship Supply ChainsGraphical AbstractVerified
Chinese Journal of Environmental Engineering2026

Life-Cycle Carbon Footprint Assessment and Emission Reduction Strategy Analysis of Ship Supply Chains

The shipping industry's carbon emissions have drawn increasing attention. This study quantifies the carbon footprint of ship supply chains across their life cycle to identify key emission stages and reduction potentials, promoting green transformation. Based on life-cycle theory and using process analysis, a carbon footprint assessment model was constructed covering raw material acquisition, construction and assembly, transportation and distribution, and scrapping and recycling. The model was applied to a case ship, followed by multi-scenario and sensitivity analyses. Results show that the transportation and distribution stage is the dominant source of positive emissions, accounting for 88.73% of the total, while the scrapping and recycling stage provides a carbon offset benefit of 6.77%. Among five emission reduction scenarios—low-carbon materials, green energy, green logistics, circular economy, and comprehensive low-carbon—the reduction efficiencies are 2.02%, 0.06%, 18.44%, 0.42%, and 20.95%, respectively, indicating that green logistics is the core pathway for decarbonizing ship supply chains. Under the green logistics scenario, optimizing the LNG carbon emission factor yields more significant reduction effects. This study provides a life-cycle perspective on the carbon footprint structure of ship supply chains, offering theoretical references for identifying key reduction links and optimizing low-carbon technology pathways.

Read Full Abstract10.12030/j.cjee.202510039
SinoGreenTech ResearchChinese Journal of Environmental Engineering
Chinese Journal of Environmental Engineering2026

Electrocatalytic Oxidation Performance and Mechanism of Porous Active Metal Oxide Coated Anode for Congo Red Degradation

To address the challenges of high salinity, recalcitrance, limited mass transfer, and coating detachment in traditional anodes for textile wastewater treatment, a porous RuO2@r-TiO2 nanotube array (NTA) anode was fabricated via anodic oxidation, electrochemical reduction, and thermal decomposition. A flow-through electrochemical oxidation system was constructed using this anode and a graphite felt cathode. The material's morphology and physicochemical properties were characterized by SEM, XRD, and XPS. Congo red (CR) was used as a model pollutant to evaluate degradation performance under various conditions. Optimal conditions were identified as current density 5 mA·cm−2, permeate flux 480 L·(m2·h)−1, initial CR concentration 0.15 mmol·L−1, and NaCl concentration 75 mmol·L−1. Under these conditions, the system achieved 91% decolorization within 20 min and 82% mineralization within 60 min. Mass transfer tests showed a rate constant of 2.23×10−4 m·s−1 in flow-through mode, three times higher than conventional mode, with active chlorine and H2O2 production increased by 32.8% and 66.7%, respectively. Radical quenching experiments indicated that singlet oxygen (1O2) was the primary reactive species. The degradation mechanism was proposed based on quenching and UV spectral analysis. The system achieved >90% decolorization for five typical dye pollutants with an energy consumption of only 0.16 kWh·m−3. Cyclic voltammetry confirmed long-term stability. These findings provide theoretical support for applying electrochemical advanced oxidation to high-salinity textile wastewater.

Read Full Abstract10.12030/j.cjee.202506064
Effect of Three-Stage Reflux Ratio on the Performance of AAOA-MBR Process for Municipal Wastewater TreatmentGraphical AbstractVerified
Chinese Journal of Environmental Engineering2026

Effect of Three-Stage Reflux Ratio on the Performance of AAOA-MBR Process for Municipal Wastewater Treatment

The AAOA-MBR (anaerobic-anoxic-oxic-anoxic membrane bioreactor) process is widely used in municipal wastewater treatment, but its multi-stage internal recirculation complicates sludge retention time (SRT) and carbon source distribution. This study systematically regulated three reflux ratios (R1: membrane tank to oxic tank; R2: oxic tank to anoxic I tank; R3: anoxic II tank to anaerobic tank) in a pilot-scale system (0.24 m3·d−1) to reveal their effects on nutrient removal and membrane fouling. When R1:R2:R3 = 300%:200%:100%, effluent COD, TN, TP, and NH3-N met discharge standards. Reducing R1 and R2, thereby decreasing total reflux ratio from R=6 to R=3, shortened SRT, which suppressed nitrifier accumulation and increased effluent COD and TN, but decreased TP. High-throughput sequencing of anoxic I and oxic tanks showed that denitrifying bacteria (Thauera and Ottowia) relative abundances decreased from 0.68% to 0.42% and 0.51% to 0.24%, respectively, while the phosphorus-accumulating organism Candidatus_Accumulibacter increased from 0.78% to 1.12%, enhancing phosphorus removal. Additionally, lowering R1 to 200% caused sludge accumulation in the membrane tank, exacerbating membrane fouling. Thus, internal recirculation ratios must be adjusted based on influent characteristics to balance nutrient removal and membrane performance.

Read Full Abstract10.12030/j.cjee.202509020
Spatiotemporal Distribution of Nutrients and Chlorophyll-a in Dongping Lake Based on Delft3D ModelingGraphical AbstractVerified
Chinese Journal of Environmental Engineering2026

Spatiotemporal Distribution of Nutrients and Chlorophyll-a in Dongping Lake Based on Delft3D Modeling

To investigate the spatiotemporal distribution of nutrients and chlorophyll-a (Chl-a) in Dongping Lake, a coupled hydrodynamic-water quality-ecological model was developed using Delft3D. The model simulated total nitrogen (TN), nitrate nitrogen (NO3-N), ammonia nitrogen (NH4-N), total phosphorus (TP), soluble reactive phosphorus (SRP), and Chl-a. After validation, the model systematically analyzed the spatiotemporal patterns and influencing factors, revealing nitrogen and phosphorus transformation pathways. Results showed three temporal phases: relatively stable concentrations from January to April, significant fluctuations from May to August, and gradual stabilization from September to December, with peak timing varying among indicators. Spatially, concentrations were generally higher in the south and lower in the north, but NH4-N, TP, and Chl-a exhibited reverse patterns (higher in north) during certain periods. External inputs, primarily from the Dawen River, dominated the overall distribution, while water temperature, dissolved oxygen, and hydrodynamic conditions further modulated internal variability. Nitrogen and phosphorus showed distinct fates: nitrogen was primarily removed via denitrification and anammox, whereas phosphorus tended to transform into particulate forms and remained in the lake for extended periods. These findings provide scientific support for precise water quality management in Dongping Lake.

Read Full Abstract10.12030/j.cjee.202510013
Mechanistic Study on Photosynthetic Bacteria Granulation under Synergistic Hydraulic and Organic LoadingGraphical AbstractVerified
Chinese Journal of Environmental Engineering2026

Mechanistic Study on Photosynthetic Bacteria Granulation under Synergistic Hydraulic and Organic Loading

Photosynthetic bacteria (PSB) wastewater treatment technology is promising for simultaneous pollutant removal and resource recovery (e.g., single-cell protein, hydrogen). However, poor cell hydrophobicity and aggregation lead to low biomass retention and short sludge retention time, hindering engineering application. This study investigated the driving role and mechanism of upflow velocity as a key hydraulic selection pressure on PSB granulation under stepwise increasing organic loading rate (OLR). In laboratory up-flow photobioreactors (UPBR), comparative experiments were conducted with macro-index monitoring and micro-mechanism analysis. Results showed that under high upflow velocities of 3.00–6.30 m·h−1, PSB granular sludge with an average diameter of 285.58 μm and excellent settleability (sludge volume index, SVI = 22.73 mL·g−1) was successfully formed within approximately 60 days. Compared to the control, the granules in the experimental group were larger, with clear boundaries and compact structure, and significant enrichment of filamentous bacteria was observed. Mechanism analysis indicated that OLR provided nutritional driving force for microbial growth, while upflow velocity supplied high hydraulic shear force, physically screening and enriching settleable aggregates, and specifically inducing secretion of hydrophobic tryptophan-like proteins and humic acids (key extracellular polymeric substances, EPS). Additionally, core genera such as Xanthobacteraceae, possessing stress tolerance and EPS secretion functions, were enriched. This study reveals a chain mechanism of 'physical selection–biological response' centered on hydraulic selection, demonstrating that upflow velocity is a key controllable factor for PSB granulation, providing theoretical basis and technical pathway for solving PSB biomass washout and promoting resource-oriented treatment of high-strength organic wastewater.

Read Full Abstract10.12030/j.cjee.202511051
Low-Temperature Thermal Remediation of Naphthalene-Contaminated Soil Using Cu–CeOx/TiO2 Trimetallic CatalystsGraphical AbstractVerified
Chinese Journal of Environmental Engineering2026

Low-Temperature Thermal Remediation of Naphthalene-Contaminated Soil Using Cu–CeOx/TiO2 Trimetallic Catalysts

Traditional soil thermal remediation requires high temperatures (>300 °C), which can damage soil structure, increase energy consumption, and elevate carbon emissions. This study developed a Cu–CeOx/TiO2 trimetallic catalyst to enable low-temperature thermal remediation of naphthalene-contaminated soil. Using nano-TiO2 as a support, catalysts with varying Cu/Ce ratios were prepared via impregnation-calcination. Material characterization (XRD, TEM, XPS, etc.) revealed that Cu and Ce incorporation induced crystal defects in TiO2, enhancing lattice oxygen activity and electron mobility, thereby generating more oxygen vacancies and hydroxyl radicals. Performance evaluation using a TGA-GC-FTIR-MS platform showed that the catalyst with Cu:Ce = 1:1 achieved the best remediation efficiency, reducing the thermal remediation temperature from 250 °C to 211.5 °C and increasing the removal rate by an average of 19.49% compared to the non-catalyst group at the same temperature. The catalyst facilitated stepwise degradation of naphthalene into smaller organic molecules (alcohols, carboxylic acids, aldehydes) and ultimately into H2O and CO2. This work demonstrates that Cu–CeOx/TiO2 significantly lowers the energy demand of thermal remediation, offering a promising approach for low-carbon remediation of organic-contaminated soils.

Read Full Abstract10.12030/j.cjee.202508081
Simulation and Prediction of Vegetation Carbon Flux under SSP Scenarios in BeijingGraphical AbstractVerified
Chinese Journal of Environmental Engineering2026

Simulation and Prediction of Vegetation Carbon Flux under SSP Scenarios in Beijing

To reveal the dynamic characteristics of ecosystem carbon flux and its response to meteorological factors, this study employed the Biome-BGC model to simulate gross primary productivity (GPP) and net primary productivity (NPP) of vegetation in Beijing for historical (2001–2014) and future (2051–2070) periods under SSP126 and SSP585 scenarios, using multi-source data including regional meteorology, vegetation type, and soil texture. The Mann-Kendall (M-K) test and Empirical Orthogonal Function (EOF) analysis were applied to examine spatiotemporal patterns and carbon use efficiency (CUE). Results indicate that Biome-BGC accurately reproduces historical carbon flux characteristics. Temporally, annual mean GPP and NPP exhibited fluctuating upward trends, ranging from 584 to 777 g C m−2 a−1 and 238 to 388 g C m−2 a−1, respectively. Spatially, GPP and NPP displayed both same-phase and opposite-phase distribution patterns. Annual mean temperature was the dominant factor influencing GPP and NPP trends, followed by solar radiation and precipitation. Under future scenarios, both GPP and NPP are projected to increase, with SSP585 showing greater enhancement. By 2070, GPP is expected to rise by 171 and 376 g C m−2 a−1 under SSP126 and SSP585, respectively, while NPP increases by 71.8 and 137 g C m−2 a−1. The spatial distribution of GPP and NPP exhibits a 'low-center, high-periphery' pattern, with multi-year means of 969 and 425 g C m−2 a−1. Future CUE is approximately 0.45, indicating substantial carbon sequestration potential of Beijing's vegetation under climate change.

Read Full Abstract10.12030/j.cjee.202509047
Enhanced Performance of Bioelectrochemical Systems Using Natural Source Materials for Methyl Orange Wastewater TreatmentGraphical AbstractVerified
Chinese Journal of Environmental Engineering2026

Enhanced Performance of Bioelectrochemical Systems Using Natural Source Materials for Methyl Orange Wastewater Treatment

To enhance the electricity generation and decolorization efficiency of bioelectrochemical systems (BES) for azo dye wastewater, this study introduced pomelo peel biochar as anode material and flavonoid-rich Chinese herbal medicines as electron mediators (EMs) into microbial fuel cells (MFCs). The anodes were prepared by chemical activation with KOH, ZnCl2, and H3BO3, followed by polypyrrole (PPy) modification. Among the modified anodes, PPy-PPCH3BO3-CC exhibited the best electrochemical performance. The EMs were derived from aqueous extracts of Scutellaria baicalensis (Huangqin), Ginkgo biloba leaves, and Pueraria lobata (Gegen). The extract from Scutellaria baicalensis showed the highest electron transfer capability. In the MFC system equipped with the optimal anode and Scutellaria baicalensis extract, the maximum output voltage reached (587±10) mV, power density increased to 423.12 mW·m−2, Coulombic efficiency was (57.85±1.06)%, COD removal efficiency was (77.45±0.92)%, charge transfer resistance (Rct) decreased to 7.15 Ω, and methyl orange decolorization rate reached (95.86±1.12)%. These results were significantly superior to the control group, demonstrating that natural source materials can effectively enhance the performance of BES for methyl orange wastewater treatment.

Read Full Abstract10.12030/j.cjee.202509019
Continuous Performance of Permeable Reactive Columns Combining ZVI/FeS2 with Microorganisms for Removal of Nitrate and Ofloxacin from WaterGraphical AbstractVerified
Chinese Journal of Environmental Engineering2026

Continuous Performance of Permeable Reactive Columns Combining ZVI/FeS2 with Microorganisms for Removal of Nitrate and Ofloxacin from Water

Groundwater contamination by nitrate and antibiotics has become a global concern. This study evaluated the continuous performance of permeable reactive barrier (PRB) columns packed with zero-valent iron (ZVI) and pyrite (FeS2) combined with denitrifying microorganisms (ZFM) for simultaneous removal of nitrate and ofloxacin (OFL). Control columns included soil (S), microorganisms (M), and ZVI/FeS2 (ZF). Over 30 days of continuous operation, the ZFM column achieved average removal efficiencies of 88% for nitrate and 78% for OFL, significantly higher than controls. The ZFM system maintained higher active iron concentration (0.68 mg·L−1) compared to ZF (0.48 mg·L−1), mitigated pH increase, and sustained lower oxidation-reduction potential (ORP), favoring stable performance. XRD and XPS analyses revealed that microbial involvement promoted FeS formation (2θ=30.1°) and reduced ZVI passivation, extending material lifespan. High-throughput sequencing showed that while overall microbial diversity remained stable, key functional populations including norank_f_Fermentibacteraceae, norank_f_Anaerolineaceae, Longilinea, and Anaerolinea increased in abundance by 2.93%, 0.55%, 1.53%, and 0.62%, respectively, enhancing nitrate and OFL removal. These findings demonstrate that integrating microorganisms with ZVI/FeS2 in PRB systems offers a promising approach for remediating combined nitrate and antibiotic contamination in groundwater.

Read Full Abstract10.12030/j.cjee.202509086
Occurrence Characteristics, Source Analysis, and Beach Quality Assessment of Marine Litter in Daya BayGraphical AbstractVerified
Chinese Journal of Environmental Engineering2026

Occurrence Characteristics, Source Analysis, and Beach Quality Assessment of Marine Litter in Daya Bay

Marine litter poses a significant threat to coastal ecosystems globally, necessitating a comprehensive understanding of its multi-compartment distribution and driving mechanisms for effective management. This study investigated the occurrence, composition, and sources of beach, sea surface, and seafloor litter in the northeastern Daya Bay, a semi-enclosed bay, during August–October 2024. Sampling included 11 beach transects, 6 surface transects, and 25 seafloor transects. Results showed that the mean density of large and very large beach litter was 4.41×10^5 items·km−2, while medium beach litter reached 5.39×10^6 items·km−2. Surface litter densities were 5.82×10^2 and 9.90×10^3 items·km−2 for large/very large and medium fractions, respectively. Seafloor litter averaged 5.20×10^3 items·km−2. Plastics dominated all compartments, accounting for 74.0% (beach), 96.0% (surface), and 78.8% (seafloor) of total litter. Source apportionment using NOWPAP methodology indicated that beach and surface litter primarily originated from coastal recreational activities, whereas seafloor litter was mainly derived from shipping and fishing. Beach quality assessment revealed that 63.6% of beaches were moderately clean or better (grade II–IV), and 90.9% were moderately safe or better (grade I–III). Hotspots included tourism beaches, tidal gyre areas, coral reef zones, and fishing grounds. The study underscores the need for targeted management, including improved waste collection on tourist beaches, dynamic cleaning protocols, and port reception facilities for fishing waste.

Read Full Abstract10.12030/j.cjee.202509067
Elimination of Matrix Effects in Ionizing Radiation Treatment of Cephalosporin Wastewater by Pretreatment CouplingGraphical AbstractVerified
Chinese Journal of Environmental Engineering2026

Elimination of Matrix Effects in Ionizing Radiation Treatment of Cephalosporin Wastewater by Pretreatment Coupling

Ionizing radiation (IR) is an emerging advanced oxidation process for degrading recalcitrant organic pollutants in water, but its efficiency is often hampered by matrix effects from coexisting substances in real wastewater. This study coupled three pretreatments—coagulation sedimentation, adsorption, and biological oxidation—with electron beam IR to treat a model cephalosporin wastewater containing cefotaxime sodium (CTX) and typical coexisting components. The results showed that all coupled systems significantly improved treatment performance compared to direct IR: COD removal increased by 19%–42% and CTX removal by 8.4%–19%. Under the tested conditions, the optimal coagulant was polymeric ferric sulfate (PFS), the optimal adsorbent was activated carbon, and the optimal aeration time for biological oxidation was 6 h. All three pretreatments reduced matrix effects, with adsorption, biological oxidation, and coagulation sedimentation lowering the matrix effect by 17%, 11%, and 9%, respectively. Quantum chemical calculations and LC-MS analysis predicted radical reaction sites on CTX and revealed five possible degradation pathways. The study demonstrates that pretreatment-IR coupling is an effective strategy to mitigate matrix effects and enhance the targeted degradation of antibiotics in complex wastewater matrices.

Read Full Abstract10.12030/j.cjee.202511034
Water Quality Assessment and Driving Mechanism Analysis of the Hanjiang River Basin Based on WQI-PCA-OPGDGraphical AbstractVerified
Chinese Journal of Environmental Engineering2026

Water Quality Assessment and Driving Mechanism Analysis of the Hanjiang River Basin Based on WQI-PCA-OPGD

To reveal the spatiotemporal evolution and driving mechanisms of water quality in the Hanjiang River Basin, this study utilized monthly water quality monitoring data from 54 sections from January 2021 to April 2024. Methods including single-factor index, comprehensive water quality index (WQI), principal component analysis (PCA), and optimal parameters-based geographical detector (OPGD) were employed. Results indicated significant spatiotemporal differences, with total nitrogen (TN), chemical oxygen demand (COD), and permanganate index (CODMn) as major pollutants, TN being the most critical. Temporally, agricultural non-point source organic pollution dominated in wet season, while comprehensive organic pollution with industrial point source characteristics prevailed in dry season. Spatially, water quality deteriorated along the main stream, with tributary downstream areas showing severe pollution, forming a pattern of 'mountainous areas good, plains poor'. OPGD revealed combined effects of natural conditions and human activities, proposing a 'zonal control and targeted treatment' strategy.

Read Full Abstract10.12030/j.cjee.202509124
Adaptive Characteristics of Paulownia fortunei to Rocky Desertification Habitats and Its Effects on Soil PropertiesGraphical AbstractVerified
Chinese Journal of Environmental Engineering2026

Adaptive Characteristics of Paulownia fortunei to Rocky Desertification Habitats and Its Effects on Soil Properties

Rocky desertification poses a severe threat to ecosystem function in karst regions of southern China. This study, conducted in Jianghua Yao Autonomous County, Hunan Province, investigated the adaptive responses of Paulownia fortunei to rocky desertification habitats and its subsequent effects on soil properties. Leaf structural and physiological parameters were measured, alongside soil physicochemical properties. Results demonstrated that P. fortunei enhanced its adaptability through increased leaf thickness (upper epidermis +50%, total +27.38%), palisade tissue thickness (+22.45%), elevated chlorophyll a (+3.55 mg·g−1) and chlorophyll b (+1.39 mg·g−1) contents, and upregulated activities of superoxide dismutase, catalase, and peroxidase. Planting P. fortunei significantly improved soil structure and fertility: soil bulk density decreased by 0.57 g·cm−3, total porosity increased by 2.41% (0–5 cm) and 3.35% (5–10 cm), field water capacity rose by 18.63% and 18.87%, capillary porosity increased by 11.45% and 14.19%, and soil organic matter content improved from Grade IV to Grade II. These findings indicate a synergistic 'plant adaptation–soil improvement' feedback mechanism, highlighting the potential of P. fortunei for ecological restoration of rocky desertification areas.

Read Full Abstract10.12030/j.cjee.202509026
Comparative Carbon Emission Assessment of Waste Plastic Valorization PathwaysGraphical AbstractVerified
Chinese Journal of Environmental Engineering2026

Comparative Carbon Emission Assessment of Waste Plastic Valorization Pathways

The escalating global generation of waste plastics necessitates robust recycling strategies to mitigate environmental impact and advance low-carbon development. This study employs life cycle assessment (LCA) and emission factor methodologies to quantify the carbon footprints of six distinct waste plastic valorization pathways: mechanical recycling, pyrolysis, alcoholysis, co-coking, solid fuel production, and direct incineration. The functional unit is one tonne of waste plastic, with system boundaries encompassing transportation, pretreatment, and resource utilization. The model accounts for indirect emissions from energy consumption, direct emissions from plastic decomposition, and carbon offsets from material or energy recovery. Results indicate that pyrolysis yields the highest carbon offset of approximately -3,024 kgCO2e per tonne, while mechanical recycling achieves an 88% material recovery rate and a net carbon offset of -991.4 kgCO2e. Net carbon emissions per tonne of waste plastic rank as follows: direct incineration (1,104 kgCO2e) > co-coking (185.8 kgCO2e) > solid fuel (115.4 kgCO2e) > alcoholysis (-259.5 kgCO2e) > mechanical recycling (-991.4 kgCO2e) > pyrolysis (-2,592 kgCO2e). These findings demonstrate that pyrolysis offers superior carbon reduction benefits compared to incineration, exhibiting a net-negative carbon footprint across its life cycle. The study provides a scientific basis for selecting low-carbon waste plastic valorization routes and informs carbon trading and emission reduction strategies in the solid waste sector.

Read Full Abstract10.12030/j.cjee.202509053
Multi-stage thermally assisted alkali activation for simultaneous self-solidification of multiple heavy metals in lithium slagGraphical AbstractVerified
Chinese Journal of Environmental Engineering2026

Multi-stage thermally assisted alkali activation for simultaneous self-solidification of multiple heavy metals in lithium slag

The rapid expansion of lithium battery industries has elevated lithium resources to strategic importance, yet lithium extraction generates 8–10 tons of slag per ton of lithium salt, with complex heavy metal content and high leaching risks. This study improves conventional alkali activation by employing a composite activator and multi-stage thermal assistance to achieve self-solidification of lithium slag, simultaneously immobilizing multiple heavy metals while producing high-strength materials. Under full slag conditions, the mechanical strength of solidified materials ranged from 3.48 to 8.25 MPa; after optimization, strength increased by 137.07%. Average immobilization rates for various heavy metals rose from 97.26% to 99.77%. In simulated acidic, alkaline, neutral, high-salt, acid rain, and leachate environments, efficient immobilization was maintained, with leachate concentrations below regulatory limits. The improved activator and thermal process reduced structural defects, promoted formation of the key Si-O-Al framework, and ensured structural integrity, enhancing both mechanical strength and heavy metal immobilization. The cost of slag solidification was approximately 185–200 CNY per ton, significantly lower than conventional methods, with low energy consumption, no high-temperature calcination, and reduced equipment and reagent requirements, supporting scalability.

Read Full Abstract10.12030/j.cjee.202510084