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Verified CAS / Academic Author2 Decoded Studies

Prof. LI Xiaoqin

School of Materials Science and Engineering, Peking University

Research Publications & English Decoded Briefs

Showing 2 publications
SCIENCE CHINA Materials2026DOI: 10.1007/s40843-026-4110-9

An Ionic Hydrogel-Based 3D Force Sensor for Multidimensional Password Input and Enhanced Security

Flexible tactile sensors are pivotal for human-machine interaction, yet accurate decoupled sensing of three-dimensional (3D) forces and integration into functional systems remain challenging. Here, we present a piezoresistive 3D force sensor based on ionic hydrogels that detects and analyzes multi-directional forces. The sensor exhibits a linear response to normal forces from 1 to 25 N (R²=0.99) and maintains stable sensitivity for shear forces within 0–4 N. By incorporating both force magnitude and direction, the sensor enables multidimensional password input, expanding traditional one-dimensional passwords into numeric, alphabetic, and Morse code formats. Experimental results demonstrate significant potential for enhancing information security. The sensor's simple structure, mature fabrication, and ease of integration with flexible electronics underscore its practicality. This work addresses the bottleneck of unidirectional sensing in conventional flexible pressure sensors, offering a robust solution for multidimensional force acquisition in human-machine interfaces, soft robotics, and biomechanical monitoring.

Environmental Chemistry2026DOI: 10.7524/j.issn.0254-6108.2025112603

Catalytic Properties of Ionic Covalent Organic Frameworks (COFs) Materials in CO2 Cycloaddition

The cycloaddition of carbon dioxide (CO2) to epoxides (CCE) is a 100% atom-economical transformation yielding cyclic carbonates, which are valuable chemical products. This reaction valorizes CO2 as a carbon feedstock, mitigating the greenhouse effect and aligning with carbon neutrality goals. Conventional covalent organic framework (COF) catalysts often require co-catalysts to achieve high efficiency. To address this, we designed and prepared a series of ionic COFs, denoted EB-BT(nOH), that simultaneously incorporate acid (hydroxyl), base (nitrogen), and nucleophilic bromide (Br−) functionalities. These materials efficiently catalyze the CCE reaction without any co-catalyst. Among them, EB-BT(OH) exhibited the highest catalytic activity, achieving a 99% yield of the target product at 120 °C and 2.0 MPa CO2 pressure. By systematically varying the hydroxyl content in the COF backbone, we investigated the critical role of hydrogen bond donors (HBDs) in the CCE reaction. This work provides new design principles for COF-based catalysts for CCE, eliminating the need for co-catalysts and enhancing process sustainability.