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Official PDF TranslationSCIENCE CHINA Materials

Unveiling Space-Charge-Regulated Etching in MAB Ceramics: A Novel Vacuum Molten Salt Strategy for Mo2AlB2

Authors: ZHANGJUE Wang; WEI Li; PENG Huang; WEIJIA Liu; WEI Yang; FAN Zhang; NANNAN Wang; CHEN Shen; CHUANMU Tian; HAILONG Wang; MI Tian; YANQIU Zhu; RUI Zhang; BINGBING Fan

DOI: 10.1007/s40843-026-4267-yStatus: Verified Translated Edition
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Key Findings in This Report

• • Minimum reflection loss of -56.3 dB at 2.4 mm thickness and effective absorption bandwidth of 6.8 GHz, representing a 2.5-fold improvement over conventional HF-etched MBenes, directly enabling lightweight radar-absorbing coatings for aerospace and 5G interference mitigation. • • Vacuum molten salt etching achieves 92% Al removal efficiency with less than 5% Mo oxidation, as confirmed by XPS depth profiling, whereas atmospheric etching yields 70% efficiency with 18% oxidation, reducing post-synthesis purification costs by an estimated 40%. • • Honeycomb-like Mo2AlB2 exhibits a specific surface area of 148 m²/g and pore volume of 0.38 cm³/g, providing abundant active sites for electromagnetic wave scattering and catalytic reactions, with thermal stability up to 600°C in air. • • The space-charge-regulated mechanism reduces etching time from 24 hours (HF-based) to 6 hours at 750°C, cutting energy consumption by 60% and enabling continuous production with a projected throughput of 50 kg/day per reactor module.