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Official PDF TranslationSCIENCE CHINA Materials

Stress-Minimizing Nano-Cones and UV-Polyurethane Synergy: Highly Transparent, Flexible Superhydrophobic Coatings with Excellent Durability

Authors: SUN Zhe; CHEN Liwei; DOU Yingying; YANG Yabin; TIAN Xuelin

DOI: 10.1007/s40843-025-3544-xStatus: Verified Translated Edition
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Key Findings in This Report

• • Retains superhydrophobicity (static contact angle 165°, sliding angle 2°) after 18,000 abrasion cycles at 20 kPa, a threshold that exceeds typical automotive clear-coat durability tests (e.g., 10,000 cycles at 10 kPa), indicating viability for exterior self-cleaning surfaces. • • Achieves 92% visible-light transmittance, 3% reflection reduction, and 0.4% haze, matching optical-grade polymer films (haze <1%) while adding superhydrophobicity, critical for solar panel cover glass where 1% transmittance gain yields ~0.8% power output increase. • • Withstands 24-hour high-speed water jetting at 2 bar and 45 tape-peeling tests (ASTM D3359 equivalent), demonstrating interfacial adhesion and mechanical resilience that surpasses most lab-scale superhydrophobic coatings (typically <10 tape peels). • • Finite element analysis confirms nano-cone geometry reduces stress concentration by an order of magnitude compared to cylindrical or spherical features, enabling the use of a UV-curable polyurethane (NOA) matrix that balances hardness and flexibility, essential for roll-to-roll manufacturing on flexible substrates.