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Single-component MXene-based sensor array generates independent and high-dimensional characteristics for discriminating volatile organic compounds

Authors: QU Danyao; LIU Taoping; WANG Zheng; JIANG Xue; REN Guancheng; WANG Jianjun; XIONG Chuqing; SU Chen; ZHANG Lu; YAO Mingshui; WANG Shaojie; ZHANG Yong; CHENG Bolang; SALIBA Walaa; HUANG Jin; HAICK Hossam; WU Weiwei

DOI: 10.1007/s40843-026-4245-4Status: Verified Translated Edition
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Key Findings in This Report

• • Single-component Ti3C2Tx MXene sensor array achieves >95% classification accuracy for VOCs (acetone, ethanol, toluene, hexane) at concentrations as low as 100 ppb, eliminating the need for multiple distinct sensing materials and reducing fabrication complexity for IoT-integrated environmental monitors. • • Limit of detection (LOD) reaches 50 ppb for acetone with response and recovery times of 12 s and 18 s, respectively, enabling real-time breath analysis for diabetes monitoring where acetone is a recognized biomarker at sub-ppm levels. • • Principal component analysis (PCA) yields 92.3% cumulative variance in the first three principal components, confirming high-dimensional feature separation that is critical for pattern recognition algorithms in portable electronic nose systems. • • Long-term stability over 30 days shows <5% signal degradation, addressing the chronic drift issue that plagues metal-oxide and polymer-based sensor arrays, thereby reducing recalibration frequency in industrial process control and smart agriculture deployments.