SinoGreenTech Academic Portal
Open AccessDOI: 10.1007/s40843-025-3616-8Original Research

Performance enhancement, negative stiffness structural characterization, and energy absorption mechanisms of 3D-printed continuous carbon fiber reinforced composites

State Key Laboratory for Manufacturing Systems Engineering, Xi'an Jiaotong University

Read Executive PreviewQuick FAQ
Performance enhancement, negative stiffness structural characterization, and energy absorption mechanisms of 3D-printed continuous carbon fiber reinforced composites
Graphical Abstract / Figure
Published In
SCIENCE CHINA Materials
Published:January 15, 2026Edition:Vol. 69, Issue 2 • pp. 100-112Citation:Yaru Zhang et al. (2026), SCIENCE CHINA Materials
Impact Factor3.5 (Q2 Scopus)
Source Journal中国科学: 材料

Key Takeaways & Executive Findings

  • • • Wet twisting of continuous carbon fiber (CCF) significantly enhances mechanical properties of CCF/PLA/PVDF composites, with failure mode shifting from fiber pull-out to characteristic fiber breakage, indicating improved interfacial adhesion. • • The optimized G-code and contour bias path redirect force distribution, enabling effective utilization of CCF properties in 3D-printed structures. • • Abaqus simulations confirm the deformation process and energy absorption mechanisms of the CCFRTP cosine beam structure, validating its feasibility for energy-absorbing applications. • • The double-cell array configuration validates the negative stiffness honeycomb structure's potential for large deformation energy absorption, with performance strongly influenced by interface properties and structural parameters.

Abstract

Negative stiffness (NS) structures exploit multi-stable mechanisms to achieve energy absorption, yet their practical application is limited by material and manufacturing constraints that compromise load-bearing capacity, reusability, and energy absorption efficiency. This study addresses these limitations by employing continuous carbon fiber reinforced thermoplastic polymers (CCFRTP) and three-dimensional (3D) printing to fabricate NS structures with cosine beam cells. A wet twisting method for continuous carbon fiber (CCF) was developed to enhance mechanical properties and elucidate failure behaviors and interfacial adhesion mechanisms. The resulting CCF/PLA/PVDF composites exhibited significant improvements in mechanical properties compared to untreated counterparts, with failure analysis revealing characteristic fiber breakage due to enhanced interfacial adhesion, as opposed to fiber pull-out and irregular fracture in untreated samples. A one-stroke path planning model was used to investigate bistability principles and energy absorption mechanisms. Displacement-controlled loading/unloading experiments assessed energy absorption in both energy-locked and repetitive modes. A dual-unit assembly structure was fabricated to validate the feasibility of a negative stiffness honeycomb structure. Composite layup simulations via Abaqus confirmed the deformation process and energy absorption mechanisms. The findings demonstrate that CCFRTP-based NS structures offer considerable potential for large deformation energy absorption applications in aerospace and naval fields.

1. Introduction

Conventional energy-absorbing structures rely on plastic deformation, ceramic fragmentation, or viscoelastic dissipation, each with inherent drawbacks. Plastic deformation, common in automotive bumpers and ceramic composite armor, offers high specific energy absorption but suffers from destructive, non-reusable deformation. Viscoelastic structures, such as those in helmet protectors, allow multiple cycles but exhibit rate-dependent performance, underperforming at low-speed, low-frequency loads. These limitations drive the search for structures that combine high energy absorption with repeatability.

Negative stiffness (NS) structures, leveraging multi-stable mechanisms and flexural step effects, present a promising alternative, achieving large deformations while maintaining reusability. However, existing NS implementations are constrained by material and manufacturing limitations, hindering load-bearing capacity and energy absorption efficiency. This study addresses these bottlenecks by employing continuous carbon fiber reinforced thermoplastic polymers (CCFRTP) and 3D printing to fabricate NS structures with cosine beam cells. A wet twisting method for continuous carbon fiber enhances mechanical properties and interfacial adhesion, while a one-stroke path planning model optimizes the structure's bistability. This approach aims to overcome prior limitations and validate the feasibility of CCFRTP-based NS honeycomb structures for demanding aerospace and naval applications.

SinoTechIntel Interactive Document Reader
Page 1–5 of Preview
100%
Download Full PDF

Loading authentic research manuscript (Pages 1–5)...

Cite This Research Paper
Yaru Zhang, Wenkai Zheng, Wenhua Guo, Yuzhong Wang, Kaiyue Ma, Qianyu Ji, Yuhang Xue, Bingheng Lu (2026). Performance enhancement, negative stiffness structural characterization, and energy absorption mechanisms of 3D-printed continuous carbon fiber reinforced composites. SCIENCE CHINA Materials. https://doi.org/10.1007/s40843-025-3616-8
SinoGreenTech Academic & Legal Disclaimer

Research & Educational Purpose Only: The translations, structured abstracts, analytical annotations, and data reports provided by SinoGreenTechare intended exclusively for academic research, internal corporate R&D, and educational benchmarking. They do not constitute formal engineering, chemical safety, legal, or professional advice.

Copyright & Intellectual Property Notice: Original copyright of the underlying source articles and experimental data remains with the respective authors, institutions, and original publishing journals. SinoGreenTech claims intellectual property only over its proprietary translations, analytical syntheses, and AEO structured enhancements in accordance with international fair use and academic citation principles.

Frequently Asked Questions

What specific mechanical property improvements were observed in wet twisted CCF/PLA/PVDF composites compared to untreated counterparts?

The wet twisted prints exhibited significant increases in mechanical properties, with failure analysis showing characteristic fiber breakage due to improved interfacial adhesion, in contrast to untreated prints which displayed fiber pull-out and irregular fracture morphologies.

How does the one-stroke path planning model contribute to the bistability and energy absorption of the cosine beam structure?

The one-stroke path planning model optimizes the G-code and implements a contour bias path to redirect force distribution, effectively utilizing CCF properties. This enables the structure to exhibit bistable behavior and efficient energy absorption, as confirmed by displacement-controlled experiments and Abaqus simulations.

What are the energy absorption characteristics of the CCFRTP cosine beam structure in energy-locked and repetitive modes?

Displacement-controlled loading/unloading experiments assessed energy absorption in both modes. The structure's performance was significantly influenced by interface properties and structural parameters, with differences observed between energy locking and repetitive energy absorption modes.

How was the feasibility of the negative stiffness honeycomb structure validated?

A dual-unit assembly structure was fabricated and tested, demonstrating overall deformation and energy absorption properties. This validated the feasibility of the negative stiffness honeycomb structure for large deformation energy absorption applications.

What are the potential applications of this CCFRTP-based negative stiffness structure?

The structure shows considerable potential for aerospace and naval applications requiring efficient energy absorption under large deformation and high loading conditions.

Related Chinese Research & Cross-Citations

Research Citation2026
Ammonium Vanadate Cathodes in Aqueous Zinc-Ion Batteries: Design Strategies and Research Progress

Ammonium Vanadate Cathodes in Aqueous Zinc-Ion Batteries: Design Strategies and Research Progress

Aqueous zinc-ion batteries (AZIBs) offer a compelling combination of high safety, environmental compatibility, and abundant zinc resources, positioning them as viable candidates for grid-scale energy storage. Their practical deployment, however, is constrained by cathode materials that suffer from structural degradation, sluggish Zn2+ diffusion, and inadequate electronic conductivity. Ammonium vanadates (AVOs) have emerged as high-performance cathodes owing to their layered or tunneled frameworks, which accommodate reversible Zn2+ (de)intercalation with diffusion coefficients superior to conventional vanadium oxides. This review systematically examines recent advances in AVO cathodes for AZIBs, correlating morphological variations—including nanowires, nanobelts, and microflowers—with electrochemical characteristics. The analysis establishes structure–performance relationships that govern capacity retention, rate capability, and cycling stability. Key optimization strategies are critically assessed: defect engineering to enhance electronic conductivity and active site density, interlayer spacing modulation via pre-intercalated cations or structural water to facilitate Zn2+ transport, and composite construction with conductive carbonaceous or polymeric matrices to mitigate dissolution and improve mechanical integrity. Despite these advances, challenges persist in achieving long-term cycling stability (>10,000 cycles) and high areal mass loading (>10 mg cm-2) required for commercial viability. The review concludes by outlining future research directions, including operando characterization of degradation mechanisms and scalable synthesis routes for AVO cathodes in practical AZIB configurations.

Examine Full Data & PDF
Research Citation2026
Microenvironment-responsive therapeutic platforms: Innovations for spinal cord injury repair

Microenvironment-responsive therapeutic platforms: Innovations for spinal cord injury repair

Spinal cord injury (SCI) remains a formidable clinical challenge due to the complex, dynamic lesion microenvironment that impedes axonal regeneration and functional recovery. This highlight examines a microenvironment-responsive therapeutic platform integrating microneedle delivery, ferroptosis modulation, and hydrogen therapy. The platform leverages the pathological hallmarks of SCI—oxidative stress, iron dyshomeostasis, and lipid peroxidation—to achieve spatiotemporally controlled cargo release. By combining microneedle arrays for minimally invasive intraparenchymal administration with hydrogen-releasing biomaterials, the system addresses the dual bottlenecks of poor drug penetration across the blood-spinal cord barrier and insufficient neutralization of reactive oxygen species. Ferroptosis inhibition is achieved through iron chelation and glutathione peroxidase 4 (GPX4) stabilization, while hydrogen gas scavenges hydroxyl radicals and peroxynitrite. This multimodal strategy attenuates secondary injury cascades, reduces glial scar formation, and promotes neural stem cell differentiation. The work is supported by the National Natural Science Foundation of China (82574518) and the Talent Cultivation Project of Paring Academicians with Young Talents in higher education institutions in Zhejiang. The authors declare no conflict of interest. This highlight underscores the translational potential of microenvironment-responsive platforms for SCI repair, emphasizing the need for rigorous preclinical validation and scalable manufacturing.

Examine Full Data & PDF
Research Citation2026
Dual-Site Adsorption over Phosphorus-Doped Copper Oxide for Efficient CO2 Electroreduction to Ethylene

Dual-Site Adsorption over Phosphorus-Doped Copper Oxide for Efficient CO2 Electroreduction to Ethylene

Electroreduction of CO2 to ethylene offers a promising route for renewable electricity storage, yet achieving high ethylene selectivity at industrial current densities remains challenging due to the large energy barrier for C–C coupling. Here, we report a “MOF-assisted in situ doping” strategy to introduce the oxophilic nonmetal phosphorus (P) into the copper oxide (CuO) lattice, constructing a localized Cu–P dual-site adsorption configuration for the key *OCCHO intermediate. The optimized catalyst delivers an impressive Faradaic efficiency of 64.6% for ethylene with a partial current density of 646 mA cm-2. Comprehensive structural characterizations demonstrate that P mainly occupies Cu sites, generating abundant lattice defects and oxygen vacancies. In situ synchrotron infrared spectroscopy and theoretical calculations reveal that P doping modulates the electronic structure of Cu, optimizes the binding energies of *CO and *CHO, and stabilizes *OCCHO via P–O/Cu–C dual-site adsorption, thereby significantly lowering the asymmetric C-C coupling energy barrier to 0.74 eV. This work highlights a dual-site microenvironment regulation strategy for CO2-to-ethylene electroreduction.

Examine Full Data & PDF
Research Citation2026
Hydrophilic Single-Atom Interface Unlocks Low-Potential CO Removal on Pt in PEMFCs

Hydrophilic Single-Atom Interface Unlocks Low-Potential CO Removal on Pt in PEMFCs

Proton exchange membrane fuel cells (PEMFCs) fed with reformate hydrogen suffer severe anode poisoning by trace CO, necessitating high CO electrooxidation potentials that degrade performance and durability. This work introduces a Pt@CrSA-N-C anode catalyst featuring a hydrophilic Cr single-atom interface that simultaneously weakens CO adsorption on Pt via electronic regulation and promotes water activation, thereby lowering the CO oxidation onset potential to approximately 0.13 V vs. RHE. The onset potential was determined by two independent methods: the first potential at which the background-corrected current exceeds 0 mA cm-2 during CO oxidation reaction tests in a three-electrode system, and the potential at which the forward scan current exceeds the N2 background current in CO-stripping voltammetry. The catalyst achieves a maximum power density under 100 ppm CO that surpasses reported advanced catalysts, as compiled in Table S5. Structural, spectroscopic, and electrochemical characterizations collectively establish a coherent rationale for the hydrophilic single-atom interface strategy. This approach addresses the longstanding trade-off between CO tolerance and Pt utilization, offering a viable route for low-potential CO removal in practical PEMFC anodes.

Examine Full Data & PDF
Research Citation2026
An Ionoelastomer-Based Bioinspired Wearable Electronics with Tele-Perception and Tactile Sensation for Machine Learning-Assisted Rehabilitation Management

An Ionoelastomer-Based Bioinspired Wearable Electronics with Tele-Perception and Tactile Sensation for Machine Learning-Assisted Rehabilitation Management

Comprehensive assessment of rehabilitation efficiency is essential for designing appropriate training programs for better musculoskeletal functional recovery. Existing contact-receptor-dependent rehabilitation assessment systems mostly focus on assessing the restoration of muscle function by evaluating grip strength or joint flexion angle; however, parameters reflecting neuromuscular synergistic function are always overlooked. Herein, we develop an ionoelastomer-based soft artificial electroreceptor (SAER) that integrates tele-perception and tactile sensation to track the rehabilitation process, collecting signals related to approaching speed and grip strength sequentially. The SAER uses polyurethane ionoelastomer incorporated with quasi-solid conductive salt as the electric field receptor, and is integrated on a rehabilitation-training ball after assembly to establish an untethered detection device; this enables the remote capture of hand approaching parameter within a 9 cm range, followed by the quantification of grip strength when contacting and grasping. Furthermore, a data-driven assessment system is established by integrating machine learning, which accurately classifies rehabilitation efficiency into six levels; it supports for rehabilitation evaluation and training programs adjustment. Overall, the SAER-based rehabilitation management system establishes a paradigm that synergistically evaluating parameters corresponding to neuromuscular functional restoration and holds strong potential for home-based active rehabilitation for minimizing dependence on frequent clinical supervision.

Examine Full Data & PDF
Research Citation2026
Microwave-Absorbing Materials with Strong Environmental Adaptability for Corrosion Protection, Anti-Icing, and Thermal Management

Microwave-Absorbing Materials with Strong Environmental Adaptability for Corrosion Protection, Anti-Icing, and Thermal Management

Microwave-absorbing materials (MAMs) deployed on naval vessels, aerospace vehicles, and critical electronic systems face coupled electromagnetic, marine salt-spray corrosion, and extreme-temperature loads that legacy single-function absorbers cannot withstand. This review consolidates progress on three environmentally adaptive MAM classes: corrosion-protective, anti-icing, and thermal-management absorbers. The electromagnetic loss and impedance-matching fundamentals are first established, then the synergistic mechanisms, design strategies, and characterization protocols for each class are examined against representative material systems and their measured performance. The analysis identifies a shared design logic—multiscale hierarchical architecture, interfacial polarization engineering, and multifunctional phase integration—while distinguishing the divergent protection mechanisms: barrier and passivation effects for corrosion, surface-energy and latent-heat regulation for anti-icing, and phonon–electron transport decoupling for thermal management. Persistent bottlenecks include the trade-off between impedance matching and protective-layer density, the absence of standardized coupled-field test protocols, and the scarcity of long-term salt-spray and thermal-cycling durability data. Future directions are delineated: intelligent self-adaptive absorbers, multiphysics-coupled simulation frameworks, and environmentally benign multifunctional integration. The review provides a theoretical and technical basis for the design, construction, and engineering scale-up of next-generation high-performance absorbers for aerospace, electronic, and marine equipment.

Examine Full Data & PDF