Multi-stimuli-responsive phase change hydrogels with dynamic fluorescence chromism based on AIE hydrophobic carbon dots for advanced encryption
Authors: ZHU Jinliang; SUN Xiaohan; ZHOU Jiazuo; LIU Yifan; JI Xinyao; WANG Fangmiao; LI Congteng; TIAN Xue; DONG Xin; BA Shuaijie; YANG Haiyue; WANG Chengyu
• • The hydrogel exhibits a tensile modulus swing from 6.28 MPa (molten) to 36.23 MPa (crystalline), enabling mechanically tunable matrices for adaptive device integration.
• • Light transmittance switches between 42% and 87% across the phase transition, providing an optical readout for encryption states.
• • After five consecutive shape-memory cycles, the recovery ratio (Rr) and fixity ratio (Rf) remain above 96%, confirming durability for repeated use in anti-counterfeiting labels.
• • Solvent exchange triggers fluorescence color shift from blue to red, enabling multi-level optical encryption beyond single-wavelength systems.