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Laser-Engraved Multilevel Encryption Enabled by FRET-Based Tunable Multicolor Polymeric Afterglow Materials

Authors: Xuhui Zhu; Jinting Huang; Yizhi Lin; Baoyu Wang; Shaolin Lu; Shuidong Chen; Zhaowei Lan; Dengchong Feng; Xirui Gu; Zetong Ma; Zhongke Yuan; Yuzhao Yang; Xudong Chen

DOI: 10.1007/s40843-025-3540-yStatus: Verified Translated Edition
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Key Findings in This Report

• • TS-FRET between BCA2PAM and R6G enables precise color tuning, with a 1 s delayed reappearance of 'appear' after UV off, providing a time-resolved encryption dimension that thwarts static counterfeit inspection. • • Laser power variation (high vs. low) on R6G-doped BCA2PAM films produces distinct visible patterns under UV and afterglow, allowing multilevel encryption; high-power QR codes are invisible under UV but emerge after breath exposure, offering humidity-triggered authentication. • • Integration with PDMS yields luminescent elastomers, and PET adhesive tapes create tamper-evident labels with customizable branding, demonstrating mechanical robustness and adaptability for industrial labeling. • • Rewritable capability: laser-written patterns visible under UV can be erased under ambient humidity and re-encrypted with new motifs, enabling reuse and reducing material waste in high-end anti-counterfeiting applications.