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Hydroxyl-driven p-π resonance in pyrene-based COFs realizes low-power and stable nonvolatile memory devices

Authors: Pan-Ke Zhou; Cong Zhang; Chao Lin; Ziyue Yu; Yuxing Huang; Tao Zeng; Xiong Chen

DOI: 10.1007/s40843-025-4082-6Status: Verified Translated Edition
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Key Findings in This Report

• • Py-OH-based memristors achieve an ON/OFF ratio of ~10^3.45 (≈2818), enabling reliable multilevel data storage with clear read margins for high-density memory applications. • • The incorporation of –OH groups reduces operating voltage to low levels (exact value not specified in text but implied), enabling low-power operation critical for energy-constrained edge devices. • • Py-OH films exhibit excellent retention stability (exact duration not specified), ensuring data nonvolatility over extended periods, essential for long-term storage. • • The synergistic effects of p-π conjugation, intramolecular hydrogen bonds, and nanofiber morphology suppress stochastic filament overgrowth, improving device-to-device reproducibility and endurance.