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Highly stable halide perovskite quantum dots embedded in nanoporous glass via Pb2+ anchored nano-confined aqueous synthesis

Authors: Qixuan Lu; Kai Feng; Daqian Wu; Fengxian Zhou; Xiaowu Wang; Xinyi Kuang; Zeyu Zhang; Zhengzheng Liu; Zhiping Hu; Jin He; Juan Du

DOI: 10.1007/s40843-025-4067-4Status: Verified Translated Edition
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Key Findings in This Report

• • The perovskite QDs embedded in nanoporous glass exhibit exceptional stability against water, photo, and thermal stress, attributed to strong Pb–O–Si chemical bonding at the interface, which is critical for long-term operation in humid or high-temperature sensing environments. • • The emission wavelength of the perovskite-glass composite can be precisely tuned across the visible spectrum from 440 nm to 760 nm, enabling color-tunable luminescent sensors and display applications with a wide color gamut. • • By integrating green- and red-emitting perovskite NG onto a blue LED chip, stable white LEDs (WLEDs) were successfully fabricated, demonstrating the practical utility of this material system in solid-state lighting with potential for high color rendering index. • • The synthesis method employs a nano-confined aqueous approach with Pb2+ anchoring, which facilitates uniform incorporation and crystallization of perovskite QDs within the porous glass matrix, overcoming challenges of precursor infiltration and aggregation seen in other porous hosts.