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Official PDF TranslationSCIENCE CHINA Materials

Enhanced OH− Conductivity and Alkaline Stability of Anion Exchange Membranes via Pyrene Stacking Backbone for Water Electrolysis

Authors: YANG Cui; HUANG Yu; SONG Wanjie; WU Mingyue; NIE Jinyu; WANG Yaoming; WU Liang; GE Xiaolin; XU Tongwen

DOI: 10.1007/s40843-025-3504-1Status: Verified Translated Edition
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Key Findings in This Report

• • Achieves hydroxide conductivity of 160 mS/cm, a 30–50% improvement over conventional poly(aryl piperidine) AEMs (typically 80–120 mS/cm), enabling higher current densities and reduced ohmic losses in electrolyzer stacks. • • Demonstrates only 0.35% conductivity degradation after 1950 h in 2 M KOH at 80 °C, corresponding to a degradation rate of ~0.00018% h−1, which is an order of magnitude lower than typical AEMs (0.01–0.1% h−1), significantly extending membrane lifetime and reducing replacement costs. • • MEA performance reaches 2.58 A/cm2 at 1.8 V, comparable to proton exchange membrane water electrolyzers (PEMWEs) but with the advantage of non-precious metal catalysts, potentially lowering capital expenditure by 20–30%. • • Durability test shows stable operation for over 700 h, with a voltage decay rate of <5 μV/h, indicating robust mechanical and chemical stability under dynamic operation, critical for integration with intermittent renewable energy sources.