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Official PDF TranslationJournal of Fuel Chemistry and Technology

Cu3P@CuO Nanosheet Catalyst for Efficient Hydrolytic Hydrogen Production from Ammonia Borane

Authors: REN Wenting; CHEN Leiyun; SHEN Jiabei; XIE Jing; ZHAO Yudie; XU Lixin; WAN Chao

DOI: 10.3724/2097-213X.2025.JFCT.0020Status: Verified Translated Edition
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Key Findings in This Report

• • Achieved a turnover frequency (TOF) of 57.23 min−1 for ammonia borane hydrolysis at 298 K, outperforming many non-noble metal catalysts and approaching noble metal benchmarks, indicating high intrinsic activity for practical hydrogen production. • • Apparent activation energy of 44.31 kJ/mol, which is low enough to enable efficient hydrogen release under mild conditions, reducing energy input for industrial processes. • • The catalyst follows pseudo-first-order kinetics with respect to catalyst amount and pseudo-zero-order kinetics with respect to AB concentration, enabling predictable scaling and reactor design. • • The synthesis uses low-cost copper chloride and sodium hypophosphite via solvothermal and low-temperature phosphating (573 K, 2 h), offering a scalable, cost-effective route for catalyst production, critical for industrial adoption.