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Circularly Polarized Light Detection in Achiral Organic Semiconductors via Chiral Plasmonic Resonance

Authors: CHANG Wenxuan; ZHANG Siyuan; SHEN Xianfeng; ZHU Rongjiao; LI Rongjin; HU Wenping

DOI: 10.1007/s40843-025-3916-3Status: Verified Translated Edition
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Key Findings in This Report

• • Achieved a dissymmetry factor (g) of 0.35 at 515 nm in achiral organic semiconductors, a value comparable to or exceeding many intrinsically chiral systems, enabling high-contrast CPL discrimination without complex chiral synthesis. • • Nearly tenfold responsivity enhancement via chiral plasmonic resonance and hot-carrier injection, directly improving signal-to-noise ratio and sensitivity in photodetection, critical for low-light imaging and communication. • • Utilized a self-assembled monolayer of L-phenylalanine–modified gold nanoparticles, a solution-processable method that eliminates costly lithographic patterning and chiral HPLC separation, reducing manufacturing complexity and cost. • • The hybrid architecture merges plasmonic chirality with organic semiconductor versatility, offering a scalable platform for on-chip chiroptoelectronic and polarization-imaging technologies, addressing the scalability bottleneck of current CPL detectors.