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Activating Inert Atomic Sites in Heterogeneous Catalysis: Multi-Scale Design Strategies

Authors: Zijing Suo; Yuyao Sun; Jianping Lai; Lei Wang

DOI: 10.1007/s40843-026-4108-1Status: Verified Translated Edition
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Key Findings in This Report

• • Triangular-ordered Co atoms on substrates enable ampere-level durable hydrogen production (Nat Commun, 2026), demonstrating that precise atomic arrangement can activate inert sites to achieve industrial-scale current densities, critical for water electrolysis. • • Tensile strain engineering activates inert non-defect Bi sites for CO2 electroreduction (Nat Commun, 2025), achieving high activity and selectivity, offering a route to carbon-neutral fuel synthesis without noble metals. • • Asymmetric coordination engineering of MXene-based metal arrays generates high-valent metal-oxo species from peroxymonosulfate for fast water decontamination (Angew Chem, 2026), showing that microenvironment modulation can enhance Fenton-like catalysis efficiency. • • Electroreduction-driven distorted nanotwins activate pure Cu for efficient hydrogen evolution (Nat Mater, 2025), achieving performance comparable to Pt-based catalysts, which is pivotal for cost-effective green hydrogen production.