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Achieving high thermoelectric performance in n-type polycrystalline SnSe via carrier mobility enhancement

Authors: Wenjie Li; Rui Zhang; Zeqing Hu; Jiahao Jiang; Zehao Lin; Min Ruan; Jingying Sun; Jing Shuai

DOI: 10.1007/s40843-025-3750-6Status: Verified Translated Edition
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Key Findings in This Report

• • InBr3 doping elevates carrier mobility to ~20.64 cm2 V−1 s−1 in n-type polycrystalline SnSe, a critical improvement for electrical conductivity and power factor. • • Lattice thermal conductivity is suppressed to ~0.25 W m−1 K−1 via multi-scale defects (dislocations and Br-rich nanowires), enhancing phonon scattering and thermal insulation. • • A peak ZT of ~1.41 at 823 K is achieved, representing a significant advancement for medium-temperature thermoelectric applications. • • An average ZT of ~0.42 over 323–823 K indicates stable performance across a wide temperature range, essential for practical device operation.