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AB Epoxy Encapsulation-Induced Transparency in Perovskite Films for Light-Emitting Diode Applications

Authors: Jiamei Chen; Liang Chu

DOI: 10.1007/s40843-025-3552-2Status: Verified Translated Edition
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Key Findings in This Report

• • AB epoxy encapsulation induces transparency in Cs0.3MA0.7PbBr3 films via Lewis acid-base coordination, with FTIR redshift of C–O–C stretch from 1035.56 to 1018.05 cm−1 (Δν ≈ 17.5 cm−1), confirming Pb2+–ether interaction. • • XPS analysis reveals Pb 4f binding energy shift of 0.25 eV and Br 3d5/2 shift of 0.45 eV, indicating electron donation and partial Br consumption, which modifies the perovskite electronic environment. • • Grain refinement to tens of nanometers triggers a Mie-to-Rayleigh scattering transition, enhancing optical transmittance while maintaining green emission. • • Encapsulated PeLEDs achieve a maximum luminance of 12,643 cd/m2 and a breakdown voltage of 27 V, demonstrating improved operational stability without compromising brightness.