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Official PDF TranslationJournal of Fuel Chemistry and Technology

A Comprehensive Database for Ethane Dehydrogenation over Heteroatom-Doped Graphene-Supported Single-Atom Catalysts

Authors: CAO Yajie; WANG Baojun; ZHANG Riguang

DOI: 10.1016/S1872-5813(26)60688-3Status: Verified Translated Edition
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Key Findings in This Report

• • The database covers 5 metal single atoms and 51 coordination environments across 6 categories, enabling systematic screening of EDH catalysts; this breadth is critical for identifying optimal dopant-metal combinations beyond conventional M-N4 structures. • • High-throughput calculations provide elementary reaction energies, vibrational frequencies, DOS, and Bader charges, offering multi-dimensional descriptors for machine-learning model training and mechanistic interpretation. • • The structure-performance relationship 'dopant type → electronic state of active metal center → catalytic activity' is established, providing a screening criterion for rational catalyst design. • • Complete raw calculation files are provided, ensuring data transparency and reproducibility, which is essential for validating computational predictions and accelerating catalyst discovery.