SinoGreenTech Academic Portal
ZY
Verified CAS / Academic Author2 Decoded Studies

Prof. Zezhong Yang

Guangdong Guangye Environmental Protection Industry Group Co., Ltd., Guangzhou 510030, China

Co-Affiliations:Key Laboratory of Light Energy Conversion Materials of Hunan Province, College of Chemistry and Chemical Engineering, Hunan Normal University

Research Publications & English Decoded Briefs

Showing 2 publications
Journal of Environmental Engineering Technology2026DOI: 10.13205/j.hjgc.202607003

Effect of Co-firing Rate on Dewatered Sludge and Municipal Solid Waste Incineration: Pollutants Emissions, Operational Performance and Byproducts

Co-firing municipal sludge with municipal solid waste (MSW) provides a viable solution for sludge disposal. This study evaluated the effect of sludge co-firing rate (0%, 5%, and 10%) on flue gas pollutant emissions, operational performance, and incineration byproduct characteristics in a waste-to-energy plant. The results showed that under all co-firing rates, the concentrations of SO2, NOx, CO, HCl, particulate matter, and dioxins complied with the limits specified in the Standard for Pollution Control on Municipal Solid Waste Incineration (GB 18485—2014). As the co-firing rate increased from 5% to 10%, concentrations of all flue gas pollutants except NOx and HCl exhibited an upward trend. The optimal operational performance under the test conditions was achieved at a 5% co-firing rate, when the flue gas volume, fan volume, and ammonia and lime consumption were minimized. Compared to the 5% rate, increasing the co-firing rate to 10% resulted in elevated flue gas volume, fan volume, and reagent consumption. Steam production decreased from 2.778 t/t (0% co-firing rate) to 2.358 t/t (5% co-firing rate) and 2.117 t/t (10% co-firing rate), indicating a reduction in power generation efficiency with increasing sludge co-firing rates. Leaching toxicity analysis of fly ash revealed significant reductions in the leached concentrations of Zn and Pb, while those of Hg, As, Ba, and Se showed slight increases, all remaining well below regulatory limits. This study confirms the technical feasibility of directly co-firing mechanically dewatered sludge (with a moisture content of 50% to 60%) without thermal drying. A 5% co-firing rate is identified as the optimal balance between operational economy and system efficiency.

SCIENCE CHINA Materials2026DOI: 10.1007/s40843-025-3969-9

Interface Reaction Inhibition in Phosphor-in-Silica Glass for High-Performance Laser Illumination

Phosphor-in-glass (PiG) materials are promising color converters for high-power laser illumination, yet suppressing interfacial reactions between phosphor and glass matrix at elevated sintering temperatures remains a critical challenge. Here, we report a Y3Al5O12:Ce3+ (YAG:Ce) phosphor-in-silica glass (PiSG) with high SiO2 content (>85 wt%) fabricated via a Cs2CO3 flux. Incorporation of Cs2O significantly inhibits SiO2-YAG:Ce reactions, preserving internal quantum efficiency (IQE) at 97.7% of pure YAG:Ce, and achieving 88.3% IQE even after calcination at 1400°C for 2 h. In contrast, smaller alkali ions (Li+, Na+) accelerate YAG:Ce decomposition. Mechanistic studies reveal that Cs+ with large ionic radius and weak interaction with oxygen suppresses non-bridging oxygen (NBO) formation, promoting a complete silica network that limits alkali ion diffusion. Leveraging the mixed alkali effect (10% Li2O + 5% Cs2O), the PiSG exhibits enhanced hydrothermal stability, withstanding 200°C treatment for 10 h. A PiG film-sapphire device delivers 3080 lm luminous flux and 213 lm W−1 efficiency under blue laser excitation. These findings establish YAG:Ce-PiSG as a highly promising color-conversion material for high-performance laser illumination.