SinoGreenTech Academic Portal
XX
Verified CAS / Academic Author2 Decoded Studies

Prof. Xixian Xia

Central South University

Research Publications & English Decoded Briefs

Showing 2 publications
SCIENCE CHINA Materials2026DOI: 10.1007/s40843-026-4293-9

Strategies for Enhancing Multi-Properties of Medium- and High-Entropy Soft Magnetic Alloys

Traditional soft magnetic alloys (SMAs) suffer from a performance trade-off where enhancing magnetic properties often compromises mechanical and other properties, limiting their use in high-efficiency power systems and advanced electronics. The design concept of medium- and high-entropy alloys (M/HEAs) offers a pathway to overcome this limitation. By leveraging multi-principal-element compositions and tailorable microstructures, medium- and high-entropy soft magnetic alloys (M/HE-SMAs) can integrate superior soft magnetic properties with exceptional mechanical strength-ductility synergy, high electrical resistivity, good thermal stability, and excellent corrosion resistance. This article reviews design strategies for synergistic enhancement of multiple properties in M/HE-SMAs, including blending multiple ferromagnetic and non-ferromagnetic elements into solid solution, inducing local chemical order, tailoring nanoprecipitates, controlling grain size, and engineering dual/multi-phase structures. The cooperative interactions among these strategies are discussed. Potential research directions for further development and practical applications are proposed.

New Carbon Materials2026DOI: 10.1016/S1872-5805(26)61104-3

Fluorination Regulates Heat Generation in Ah-Level Lithium/Fluorinated Carbon Pouch Cells

Lithium/fluorinated carbon (Li/CFx) batteries are among the most promising high-energy-density primary batteries, yet substantial heat generation during discharge poses safety concerns, particularly for high-mass-loaded pouch cells. This study systematically investigates the effects of fluorination temperature on the structure and kinetics of fluorinated porous carbon (FPC) cathodes and on heat generation in Ah-level Li/FPC pouch cells. FPC samples with varying degrees of fluorination were synthesized by adjusting fluorination temperature, which influenced not only the F/C ratio but also the C–F bonding configuration, pore structure, and electronic transport capability. Pouch cells employing more highly fluorinated cathodes generated the most heat during discharge, with heat generation exhibiting clear stage dependence, predominantly in the 0–20% depth of discharge (DOD) range. Post-discharge structural characterization and kinetic analysis revealed that highly fluorinated FPC cathodes (FPC-250) undergo more concentrated LiF accumulation, leading to higher charge-transfer resistance, stronger polarization, lower Li+ diffusivity, and higher nucleation overpotential. These factors collectively intensify early-stage heat generation. The study establishes a correlation between fluorination temperature and cathode structure, discharge-product evolution, discharge kinetics, and heat generation, demonstrating that regulating fluorination temperature is an effective strategy for improving the thermal safety of Li/CFx batteries.