Removal Mechanisms of Fe3O4@MIL-100(Fe) for Microplastics in Water
Microplastics (MPs) are frequently detected in various water bodies, posing increasing environmental risks. This study synthesized magnetic Fe3O4@MIL-100(Fe) microspheres via an in-situ one-step hydrothermal method and investigated their adsorption removal mechanisms for polystyrene (PS) and polylactic acid (PLA) microplastics. The composite exhibited a core-shell structure with a high specific surface area of 848.6 m2·g−1. Adsorption kinetics showed that PLA followed a pseudo-second-order model, while PS fitted both pseudo-first-order and pseudo-second-order models. Equilibrium data for both MPs were well described by the Freundlich isotherm. Removal efficiencies for PLA and PS increased from 58.18% and 49.66% to 98.90% and 98.58%, respectively, as pH decreased, and from 64.24% and 21.58% to 97.05% and 94.63% with increasing ionic strength. The removal mechanism involved synergistic physical-chemical interactions: hydrogen bonding dominated for PLA, with some complexation, while π–π interactions and hydrogen bonding were primary for PS. The material demonstrated excellent reusability over multiple cycles. These findings highlight the potential of Fe3O4@MIL-100(Fe) for efficient removal of MPs from water, offering a novel approach for controlling emerging contaminants.